Adjustable interlayer spacing of ultrathin MXene-derived membranes for ion rejection

Yuqing Sun, Shilong Li, Yongxiang Zhuang, Guozhen Liu, Weihong Xing, Wenheng Jing

Research output: Contribution to journalArticlepeer-review

132 Scopus citations

Abstract

Robust lamellar membranes with adjustable interlayer spacing have exhibited exceptional permeability and play a key role in many applications. Herein, ultrathin MXene-derived membranes (thickness: 100 nm) supported on α-Al2O3 tubular supports were designed and the interlayer spacing between stacked neighboring nanosheets was finely tuned via sintering-temperature regulation. Below 400 °C, the spacing decreased from 3.71 (60 °C) to 2.68 (400 °C) and the membranes with a well-packed layer nanoarchitecture exhibited regulable ion rejection properties. The space reduction can be attributed to the moisture loss and de-functionalization (-OH) occurring within the MXene film at elevated temperatures. Along with the rise of sintering temperature, the dark green MXene layer transformed progressively into a white reflective membrane above 400 °C, owing to the oxidation of Ti3C2Tx nanosheets into TiO2 nanoparticles. This resulted in a filtration-mode change from interlayer transport pathways to longitudinal-lateral nanochannels and, hence, a reduction in ion retention. The optimal MXene-derived membranes (T400) exhibited favorable ion-rejection rate (99.2% for VO2+). Therefore, the method provides a facile and straightforward strategy for adjusting the interlayer spacing of the membranes fabricated from two-dimensional nanosheets for achieving satisfactory ion rejection.

Original languageEnglish
Article number117350
JournalJournal of Membrane Science
Volume591
DOIs
StatePublished - 1 Dec 2019

Keywords

  • Adjustable interlayer spacing
  • Ion rejection
  • MXene-derived membranes
  • Ultrathin

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