Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to α,β-unsaturated esters

Shun Yi Wang; Tze Keong Lum; Shun Jun Ji; Teck Peng Loh

doi:10.1002/adsc.200700567

Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to α,β-unsaturated esters

Shun Yi Wang, Tze Keong Lum, Shun Jun Ji, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

A highly efficient asymmetric conjugate addition of methylmagnesium bromide (MeMgBr) to α,β-unsaturated esters catalyzed by copper(I) iodide-tolyl-BNIP (CuI-Tol-BINAP) is described.

Original language	English
Pages (from-to)	673-677
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	350
Issue number	5
DOIs	https://doi.org/10.1002/adsc.200700567
State	Published - 25 Mar 2008
Externally published	Yes

Keywords

C-C bond formation
Conjugate addition
Copper(I) iodide
Methylmagnesium bromide
Tolyl-BINAP

Access to Document

10.1002/adsc.200700567

Cite this

@article{88853bfc8ab2456aa606838a4ea1eba5,

title = "Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to α,β-unsaturated esters",

abstract = "A highly efficient asymmetric conjugate addition of methylmagnesium bromide (MeMgBr) to α,β-unsaturated esters catalyzed by copper(I) iodide-tolyl-BNIP (CuI-Tol-BINAP) is described.",

keywords = "C-C bond formation, Conjugate addition, Copper(I) iodide, Methylmagnesium bromide, Tolyl-BINAP",

author = "Wang, {Shun Yi} and Lum, {Tze Keong} and Ji, {Shun Jun} and Loh, {Teck Peng}",

year = "2008",

month = mar,

day = "25",

doi = "10.1002/adsc.200700567",

language = "英语",

volume = "350",

pages = "673--677",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

publisher = "Wiley-VCH Verlag",

number = "5",

}

TY - JOUR

T1 - Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to α,β-unsaturated esters

AU - Wang, Shun Yi

AU - Lum, Tze Keong

AU - Ji, Shun Jun

AU - Loh, Teck Peng

PY - 2008/3/25

Y1 - 2008/3/25

N2 - A highly efficient asymmetric conjugate addition of methylmagnesium bromide (MeMgBr) to α,β-unsaturated esters catalyzed by copper(I) iodide-tolyl-BNIP (CuI-Tol-BINAP) is described.

AB - A highly efficient asymmetric conjugate addition of methylmagnesium bromide (MeMgBr) to α,β-unsaturated esters catalyzed by copper(I) iodide-tolyl-BNIP (CuI-Tol-BINAP) is described.

KW - C-C bond formation

KW - Conjugate addition

KW - Copper(I) iodide

KW - Methylmagnesium bromide

KW - Tolyl-BINAP

UR - http://www.scopus.com/inward/record.url?scp=51049097311&partnerID=8YFLogxK

U2 - 10.1002/adsc.200700567

DO - 10.1002/adsc.200700567

M3 - 文章

AN - SCOPUS:51049097311

SN - 1615-4150

VL - 350

SP - 673

EP - 677

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 5

ER -

Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to α,β-unsaturated esters

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this