Abstract
A stereospecific route to the key intermediate 4 for the total synthesis of dysiherbaine has been successfully developed based on the indium-mediated allylation reaction in aqueous media. Further manipulation to the advanced intermediate 28 has resulted in the discovery of a series of highly stereoselective processes.
| Original language | English |
|---|---|
| Pages (from-to) | 755-764 |
| Number of pages | 10 |
| Journal | Synthesis (Germany) |
| Issue number | 5 |
| DOIs | |
| State | Published - 2003 |
| Externally published | Yes |
Keywords
- Allylations
- Amino acids
- Indium
- Natural products
- Stereoselectivity