Indium-mediated allylation reaction in aqueous media: Synthetic studies towards the total synthesis of dysiherbaine

Jing Mei Huang, Kai Chen Xu, Teck Peng Loh

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

A stereospecific route to the key intermediate 4 for the total synthesis of dysiherbaine has been successfully developed based on the indium-mediated allylation reaction in aqueous media. Further manipulation to the advanced intermediate 28 has resulted in the discovery of a series of highly stereoselective processes.

Original languageEnglish
Pages (from-to)755-764
Number of pages10
JournalSynthesis (Germany)
Issue number5
DOIs
StatePublished - 2003
Externally publishedYes

Keywords

  • Allylations
  • Amino acids
  • Indium
  • Natural products
  • Stereoselectivity

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