Metal oxychlorides as cathode materials for chloride ion batteries

Xiangyu Zhao; Zhirong Zhao-Karger; Di Wang; Maximilian Fichtner

doi:10.1002/anie.201307314

Metal oxychlorides as cathode materials for chloride ion batteries

Xiangyu Zhao, Zhirong Zhao-Karger, Di Wang, Maximilian Fichtner

Research output: Contribution to journal › Article › peer-review

173 Scopus citations

Abstract

A key challenge of chloride ion batteries is to develop cathode materials that are stable in the electrolytes. Metal oxychlorides are presented as such a cathode material. The electrochemical performance and the reaction mechanisms of the BiOCl and FeOCl cathode were investigated. Both cathodes showed reversible reactions, including a major conversion reaction and a minor intercalation process, by chloride ion transfer during cycling.

Original language	English
Pages (from-to)	13621-13624
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	51
DOIs	https://doi.org/10.1002/anie.201307314
State	Published - 16 Dec 2013
Externally published	Yes

Keywords

chloride ions
electrochemistry
ionic-liquid electrolytes
metal oxychlorides
rechargeable batteries

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10.1002/anie.201307314

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abstract = "A key challenge of chloride ion batteries is to develop cathode materials that are stable in the electrolytes. Metal oxychlorides are presented as such a cathode material. The electrochemical performance and the reaction mechanisms of the BiOCl and FeOCl cathode were investigated. Both cathodes showed reversible reactions, including a major conversion reaction and a minor intercalation process, by chloride ion transfer during cycling.",

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author = "Xiangyu Zhao and Zhirong Zhao-Karger and Di Wang and Maximilian Fichtner",

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AU - Zhao, Xiangyu

AU - Zhao-Karger, Zhirong

AU - Wang, Di

AU - Fichtner, Maximilian

PY - 2013/12/16

Y1 - 2013/12/16

N2 - A key challenge of chloride ion batteries is to develop cathode materials that are stable in the electrolytes. Metal oxychlorides are presented as such a cathode material. The electrochemical performance and the reaction mechanisms of the BiOCl and FeOCl cathode were investigated. Both cathodes showed reversible reactions, including a major conversion reaction and a minor intercalation process, by chloride ion transfer during cycling.

AB - A key challenge of chloride ion batteries is to develop cathode materials that are stable in the electrolytes. Metal oxychlorides are presented as such a cathode material. The electrochemical performance and the reaction mechanisms of the BiOCl and FeOCl cathode were investigated. Both cathodes showed reversible reactions, including a major conversion reaction and a minor intercalation process, by chloride ion transfer during cycling.

KW - chloride ions

KW - electrochemistry

KW - ionic-liquid electrolytes

KW - metal oxychlorides

KW - rechargeable batteries

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DO - 10.1002/anie.201307314

M3 - 文章

AN - SCOPUS:84890449390

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Metal oxychlorides as cathode materials for chloride ion batteries

Abstract

Keywords

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