Nickel-Catalyzed Direct Cross-Coupling of Aryl Fluorosulfates with Aryl Bromides

Jin He Na; Xiang Liu; Jia Wen Jing; Jing Wang; Xue Qiang Chu; Mengtao Ma; Hao Xu; Xiaocong Zhou; Zhi Liang Shen

doi:10.1021/acs.orglett.3c00674

Nickel-Catalyzed Direct Cross-Coupling of Aryl Fluorosulfates with Aryl Bromides

Jin He Na, Xiang Liu, Jia Wen Jing, Jing Wang, Xue Qiang Chu, Mengtao Ma, Hao Xu, Xiaocong Zhou, Zhi Liang Shen

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A one-pot, direct cross-coupling of aryl fluorosulfate with aryl bromide, which is step-economical and avoids the use of a preprepared/commercial organometallic reagent, could be accomplished by performing the reaction in THF at room temperature in the presence of nickel catalyst, magnesium turnings, and lithium chloride, giving rise to the corresponding biaryls in moderate to good yields with reasonable functional group compatibility.

Original language	English
Pages (from-to)	2318-2322
Number of pages	5
Journal	Organic Letters
Volume	25
Issue number	13
DOIs	https://doi.org/10.1021/acs.orglett.3c00674
State	Published - 7 Apr 2023

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title = "Nickel-Catalyzed Direct Cross-Coupling of Aryl Fluorosulfates with Aryl Bromides",

abstract = "A one-pot, direct cross-coupling of aryl fluorosulfate with aryl bromide, which is step-economical and avoids the use of a preprepared/commercial organometallic reagent, could be accomplished by performing the reaction in THF at room temperature in the presence of nickel catalyst, magnesium turnings, and lithium chloride, giving rise to the corresponding biaryls in moderate to good yields with reasonable functional group compatibility.",

author = "Na, {Jin He} and Xiang Liu and Jing, {Jia Wen} and Jing Wang and Chu, {Xue Qiang} and Mengtao Ma and Hao Xu and Xiaocong Zhou and Shen, {Zhi Liang}",

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doi = "10.1021/acs.orglett.3c00674",

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T1 - Nickel-Catalyzed Direct Cross-Coupling of Aryl Fluorosulfates with Aryl Bromides

AU - Na, Jin He

AU - Liu, Xiang

AU - Jing, Jia Wen

AU - Wang, Jing

AU - Chu, Xue Qiang

AU - Ma, Mengtao

AU - Xu, Hao

AU - Zhou, Xiaocong

AU - Shen, Zhi Liang

PY - 2023/4/7

Y1 - 2023/4/7

N2 - A one-pot, direct cross-coupling of aryl fluorosulfate with aryl bromide, which is step-economical and avoids the use of a preprepared/commercial organometallic reagent, could be accomplished by performing the reaction in THF at room temperature in the presence of nickel catalyst, magnesium turnings, and lithium chloride, giving rise to the corresponding biaryls in moderate to good yields with reasonable functional group compatibility.

AB - A one-pot, direct cross-coupling of aryl fluorosulfate with aryl bromide, which is step-economical and avoids the use of a preprepared/commercial organometallic reagent, could be accomplished by performing the reaction in THF at room temperature in the presence of nickel catalyst, magnesium turnings, and lithium chloride, giving rise to the corresponding biaryls in moderate to good yields with reasonable functional group compatibility.

UR - http://www.scopus.com/inward/record.url?scp=85151386847&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.3c00674

DO - 10.1021/acs.orglett.3c00674

M3 - 文章

C2 - 36961113

AN - SCOPUS:85151386847

SN - 1523-7060

VL - 25

SP - 2318

EP - 2322

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Nickel-Catalyzed Direct Cross-Coupling of Aryl Fluorosulfates with Aryl Bromides

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