One-dimensional chain structure based on bifurcated hydrogen bonding

Ren Xiaoming; Lu Changsheng; Wu Peiheng; Meng Qingjin

doi:10.1023/A:1014371922273

One-dimensional chain structure based on bifurcated hydrogen bonding

Ren Xiaoming, Lu Changsheng, Wu Peiheng, Meng Qingjin

Nanjing University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The structure of complex [PyH][Ni(mnt)₂], as determined by X-ray single crystal analysis, consists of pyridinium cations and [Ni(mnt)₂]^- anions. Crystallographic data for the complex: monoclinic P2₁/c, a = 16.5430(18) Å, b = 6.3847(9) Å, c = 17.430(2) Å, β = 118.040(7)°, V = 1625.4(3) Å³, Z = 4. The [Ni(mnt)₂]^- anion is not a planar and the CN groups bend away from the S₄ plane. The interactions between anions and cations via the formation of bifurcated N-H⋯N≡C hydrogen bonds give rise to an 1D zigzag chain of alternating cations and anions.

Original language	English
Pages (from-to)	173-177
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	31
Issue number	3
DOIs	https://doi.org/10.1023/A:1014371922273
State	Published - Mar 2001
Externally published	Yes

Keywords

1D chain
Crystal structure
Hydrogen bonding
Maleonitriledithiolate complex

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10.1023/A:1014371922273

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title = "One-dimensional chain structure based on bifurcated hydrogen bonding",

abstract = "The structure of complex [PyH][Ni(mnt)2], as determined by X-ray single crystal analysis, consists of pyridinium cations and [Ni(mnt)2]- anions. Crystallographic data for the complex: monoclinic P21/c, a = 16.5430(18) {\AA}, b = 6.3847(9) {\AA}, c = 17.430(2) {\AA}, β = 118.040(7)°, V = 1625.4(3) {\AA}3, Z = 4. The [Ni(mnt)2]- anion is not a planar and the CN groups bend away from the S4 plane. The interactions between anions and cations via the formation of bifurcated N-H⋯N≡C hydrogen bonds give rise to an 1D zigzag chain of alternating cations and anions.",

keywords = "1D chain, Crystal structure, Hydrogen bonding, Maleonitriledithiolate complex",

author = "Ren Xiaoming and Lu Changsheng and Wu Peiheng and Meng Qingjin",

year = "2001",

month = mar,

doi = "10.1023/A:1014371922273",

language = "英语",

volume = "31",

pages = "173--177",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer",

number = "3",

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TY - JOUR

T1 - One-dimensional chain structure based on bifurcated hydrogen bonding

AU - Xiaoming, Ren

AU - Changsheng, Lu

AU - Peiheng, Wu

AU - Qingjin, Meng

PY - 2001/3

Y1 - 2001/3

N2 - The structure of complex [PyH][Ni(mnt)2], as determined by X-ray single crystal analysis, consists of pyridinium cations and [Ni(mnt)2]- anions. Crystallographic data for the complex: monoclinic P21/c, a = 16.5430(18) Å, b = 6.3847(9) Å, c = 17.430(2) Å, β = 118.040(7)°, V = 1625.4(3) Å3, Z = 4. The [Ni(mnt)2]- anion is not a planar and the CN groups bend away from the S4 plane. The interactions between anions and cations via the formation of bifurcated N-H⋯N≡C hydrogen bonds give rise to an 1D zigzag chain of alternating cations and anions.

AB - The structure of complex [PyH][Ni(mnt)2], as determined by X-ray single crystal analysis, consists of pyridinium cations and [Ni(mnt)2]- anions. Crystallographic data for the complex: monoclinic P21/c, a = 16.5430(18) Å, b = 6.3847(9) Å, c = 17.430(2) Å, β = 118.040(7)°, V = 1625.4(3) Å3, Z = 4. The [Ni(mnt)2]- anion is not a planar and the CN groups bend away from the S4 plane. The interactions between anions and cations via the formation of bifurcated N-H⋯N≡C hydrogen bonds give rise to an 1D zigzag chain of alternating cations and anions.

KW - 1D chain

KW - Crystal structure

KW - Hydrogen bonding

KW - Maleonitriledithiolate complex

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U2 - 10.1023/A:1014371922273

DO - 10.1023/A:1014371922273

M3 - 文章

AN - SCOPUS:0035560083

SN - 1074-1542

VL - 31

SP - 173

EP - 177

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 3

ER -

One-dimensional chain structure based on bifurcated hydrogen bonding

Abstract

Keywords

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