Promotional effect of phosphorylation on CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO from marine diesel exhaust

Bing HAN; Yuesong SHEN; Shemin ZHU; Youlin LIU; Shubao SHEN

doi:10.1016/S1002-0721(16)60128-X

Promotional effect of phosphorylation on CeSn_0.8W_0.6O_x/TiAl_0.2Si_0.1O_y for NH₃-SCR of NO from marine diesel exhaust

Bing HAN, Yuesong SHEN, Shemin ZHU, Youlin LIU, Shubao SHEN

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A series of phosphorylation and blank CeSn_0.8W_0.6O_x/TiAl_0.2Si_0.1O_y catalysts prepared by extrusion molding were tested for NH₃-SCR of NO, and were characterized by techniques of X-ray diffraction (XRD), Brumauer-Emmett-Teller (N₂-BET), environmental scanning electron microscope (ESEM), temperature programmed reduction (H₂-TPR) and temperature programmed desorption (NH₃-TPD). Effects of phosphorylation on catalytic activity and sulfur-resisting performance of the CeSn_0.8W_0.6O_x/TiAl_0.2Si_0.1O_y for NH₃-SCR of NO were mainly studied. Results showed that the phosphorylation improved the catalytic activity and sulfur-resisting performance in an active temperature window of 300–440 °C, and the phosphorylation catalyst with 0.4 wt.% H₃PO₄ exhibited the best catalytic performance and the strongest sulfur-resisting performance. Analysis showed that the phosphorylation increased specific surface area, enhanced the surface acidity and improved redox properties.

Original language	English
Pages (from-to)	1010-1016
Number of pages	7
Journal	Journal of Rare Earths
Volume	34
Issue number	10
DOIs	https://doi.org/10.1016/S1002-0721(16)60128-X
State	Published - 1 Oct 2016

Keywords

CeSnWO/TiAlSiO
NH-SCR
NO conversion
diesel engine exhaust
phosphorylation
rare earths
sulfur-resisting

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/S1002-0721(16)60128-X

Cite this

@article{be77faf776324ad9a63fa6b8809a5266,

title = "Promotional effect of phosphorylation on CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO from marine diesel exhaust",

abstract = "A series of phosphorylation and blank CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy catalysts prepared by extrusion molding were tested for NH3-SCR of NO, and were characterized by techniques of X-ray diffraction (XRD), Brumauer-Emmett-Teller (N2-BET), environmental scanning electron microscope (ESEM), temperature programmed reduction (H2-TPR) and temperature programmed desorption (NH3-TPD). Effects of phosphorylation on catalytic activity and sulfur-resisting performance of the CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO were mainly studied. Results showed that the phosphorylation improved the catalytic activity and sulfur-resisting performance in an active temperature window of 300–440 °C, and the phosphorylation catalyst with 0.4 wt.% H3PO4 exhibited the best catalytic performance and the strongest sulfur-resisting performance. Analysis showed that the phosphorylation increased specific surface area, enhanced the surface acidity and improved redox properties.",

keywords = "CeSnWO/TiAlSiO, NH-SCR, NO conversion, diesel engine exhaust, phosphorylation, rare earths, sulfur-resisting",

author = "Bing HAN and Yuesong SHEN and Shemin ZHU and Youlin LIU and Shubao SHEN",

note = "Publisher Copyright: {\textcopyright} 2016 The Chinese Society of Rare Earths",

year = "2016",

month = oct,

day = "1",

doi = "10.1016/S1002-0721(16)60128-X",

language = "英语",

volume = "34",

pages = "1010--1016",

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TY - JOUR

T1 - Promotional effect of phosphorylation on CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO from marine diesel exhaust

AU - HAN, Bing

AU - SHEN, Yuesong

AU - ZHU, Shemin

AU - LIU, Youlin

AU - SHEN, Shubao

PY - 2016/10/1

Y1 - 2016/10/1

N2 - A series of phosphorylation and blank CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy catalysts prepared by extrusion molding were tested for NH3-SCR of NO, and were characterized by techniques of X-ray diffraction (XRD), Brumauer-Emmett-Teller (N2-BET), environmental scanning electron microscope (ESEM), temperature programmed reduction (H2-TPR) and temperature programmed desorption (NH3-TPD). Effects of phosphorylation on catalytic activity and sulfur-resisting performance of the CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO were mainly studied. Results showed that the phosphorylation improved the catalytic activity and sulfur-resisting performance in an active temperature window of 300–440 °C, and the phosphorylation catalyst with 0.4 wt.% H3PO4 exhibited the best catalytic performance and the strongest sulfur-resisting performance. Analysis showed that the phosphorylation increased specific surface area, enhanced the surface acidity and improved redox properties.

AB - A series of phosphorylation and blank CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy catalysts prepared by extrusion molding were tested for NH3-SCR of NO, and were characterized by techniques of X-ray diffraction (XRD), Brumauer-Emmett-Teller (N2-BET), environmental scanning electron microscope (ESEM), temperature programmed reduction (H2-TPR) and temperature programmed desorption (NH3-TPD). Effects of phosphorylation on catalytic activity and sulfur-resisting performance of the CeSn0.8W0.6Ox/TiAl0.2Si0.1Oy for NH3-SCR of NO were mainly studied. Results showed that the phosphorylation improved the catalytic activity and sulfur-resisting performance in an active temperature window of 300–440 °C, and the phosphorylation catalyst with 0.4 wt.% H3PO4 exhibited the best catalytic performance and the strongest sulfur-resisting performance. Analysis showed that the phosphorylation increased specific surface area, enhanced the surface acidity and improved redox properties.

KW - CeSnWO/TiAlSiO

KW - NH-SCR

KW - NO conversion

KW - diesel engine exhaust

KW - phosphorylation

KW - rare earths

KW - sulfur-resisting

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