Shape-memory polymer composites selectively responsive to near-infrared lights of two wavelengths

Tianyu Fang; Shunping Chen; Liang Fang; Zhongzi Xu; Chunhua Lu

Shape-memory polymer composites selectively responsive to near-infrared lights of two wavelengths

Tianyu Fang, Shunping Chen, Liang Fang, Zhongzi Xu, Chunhua Lu

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to conference › Paper › peer-review

Abstract

Rare earth organic complexes of Yb(TTA)₂AAPhen and Nd(TTA)₂AAPhen were reported here as selective photothermal fillers to near infrared (NIR) lights of 980 and 808 nm, respectively. The reactive ligand of acrylic acid (AA) containing double bonds was expected to facilitate the powder dispersion in poly [ethylene-ran-(vinyl acetate)] (EVA) as a thermally-induced shape-memory polymer during the UV curing. The powders absorbed the NIR lights with certain wavelengths and converted the light energy into heat, indirectly increasing the temperature of the EVA composites. Their full shape recoveries were triggered when the temperature went beyond the switching temperature. This work introduced an approach to make use of reactive ligands to facilitate the dispersion of photothermal fillers in shape-memory polymer composites, and correspondingly provided them with the shape-memory capability upon certain NIR lights.

Original language	English
State	Published - 2017
Event	21st International Conference on Composite Materials, ICCM 2017 - Xi'an, China Duration: 20 Aug 2017 → 25 Aug 2017

Conference

Conference	21st International Conference on Composite Materials, ICCM 2017
Country/Territory	China
City	Xi'an
Period	20/08/17 → 25/08/17

Keywords

Functional polymer composites
Near-infrared light
Rare earth organic complexes
Shape-memory polymer
Smart materials

Cite this

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title = "Shape-memory polymer composites selectively responsive to near-infrared lights of two wavelengths",

abstract = "Rare earth organic complexes of Yb(TTA)2AAPhen and Nd(TTA)2AAPhen were reported here as selective photothermal fillers to near infrared (NIR) lights of 980 and 808 nm, respectively. The reactive ligand of acrylic acid (AA) containing double bonds was expected to facilitate the powder dispersion in poly [ethylene-ran-(vinyl acetate)] (EVA) as a thermally-induced shape-memory polymer during the UV curing. The powders absorbed the NIR lights with certain wavelengths and converted the light energy into heat, indirectly increasing the temperature of the EVA composites. Their full shape recoveries were triggered when the temperature went beyond the switching temperature. This work introduced an approach to make use of reactive ligands to facilitate the dispersion of photothermal fillers in shape-memory polymer composites, and correspondingly provided them with the shape-memory capability upon certain NIR lights.",

keywords = "Functional polymer composites, Near-infrared light, Rare earth organic complexes, Shape-memory polymer, Smart materials",

author = "Tianyu Fang and Shunping Chen and Liang Fang and Zhongzi Xu and Chunhua Lu",

note = "Publisher Copyright: {\textcopyright} 2017 International Committee on Composite Materials. All rights reserved.; 21st International Conference on Composite Materials, ICCM 2017 ; Conference date: 20-08-2017 Through 25-08-2017",

year = "2017",

language = "英语",

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TY - CONF

T1 - Shape-memory polymer composites selectively responsive to near-infrared lights of two wavelengths

AU - Fang, Tianyu

AU - Chen, Shunping

AU - Fang, Liang

AU - Xu, Zhongzi

AU - Lu, Chunhua

PY - 2017

Y1 - 2017

N2 - Rare earth organic complexes of Yb(TTA)2AAPhen and Nd(TTA)2AAPhen were reported here as selective photothermal fillers to near infrared (NIR) lights of 980 and 808 nm, respectively. The reactive ligand of acrylic acid (AA) containing double bonds was expected to facilitate the powder dispersion in poly [ethylene-ran-(vinyl acetate)] (EVA) as a thermally-induced shape-memory polymer during the UV curing. The powders absorbed the NIR lights with certain wavelengths and converted the light energy into heat, indirectly increasing the temperature of the EVA composites. Their full shape recoveries were triggered when the temperature went beyond the switching temperature. This work introduced an approach to make use of reactive ligands to facilitate the dispersion of photothermal fillers in shape-memory polymer composites, and correspondingly provided them with the shape-memory capability upon certain NIR lights.

AB - Rare earth organic complexes of Yb(TTA)2AAPhen and Nd(TTA)2AAPhen were reported here as selective photothermal fillers to near infrared (NIR) lights of 980 and 808 nm, respectively. The reactive ligand of acrylic acid (AA) containing double bonds was expected to facilitate the powder dispersion in poly [ethylene-ran-(vinyl acetate)] (EVA) as a thermally-induced shape-memory polymer during the UV curing. The powders absorbed the NIR lights with certain wavelengths and converted the light energy into heat, indirectly increasing the temperature of the EVA composites. Their full shape recoveries were triggered when the temperature went beyond the switching temperature. This work introduced an approach to make use of reactive ligands to facilitate the dispersion of photothermal fillers in shape-memory polymer composites, and correspondingly provided them with the shape-memory capability upon certain NIR lights.

KW - Functional polymer composites

KW - Near-infrared light

KW - Rare earth organic complexes

KW - Shape-memory polymer

KW - Smart materials

UR - http://www.scopus.com/inward/record.url?scp=85053144798&partnerID=8YFLogxK

M3 - 论文

AN - SCOPUS:85053144798

T2 - 21st International Conference on Composite Materials, ICCM 2017

Y2 - 20 August 2017 through 25 August 2017

ER -

Shape-memory polymer composites selectively responsive to near-infrared lights of two wavelengths

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