Structural and luminescent properties of Eu3+-doped double perovskite BaLaMgNbO6 phosphor

Xibing Li, Quan Liu, Wentao Huang, Sihao Chen, Lixi Wang, Mingxun Yu, Qitu Zhang

Research output: Contribution to journalArticlepeer-review

56 Scopus citations

Abstract

Eu3+-activated BaLaMgNbO6 red-emitting phosphors were synthesized by a high-temperature solid-state reaction method. Phase analysis and luminescence were characterized by X-ray diffraction (XRD) and photoluminescence excitation and emission spectra. The XRD patterns showed that BaLaMgNbO6 had a monoclinic structure with space group P21/n. The excitation spectra consisted of a broad charge-transfer band and some sharp f-f absorption peaks characteristic of Eu3+. The intensity ratio of I615/I590 was used to detect the chemical environment of Eu3+. The chromaticity coordinates of BaLa0.7Eu0.3MgNbO6 were (0.67, 0.33), indicating that the BaLaMgNbO6:Eu3+ phosphors were excellent red-emitting phosphors. Under excitation by near-ultraviolet (UV) and blue light, the phosphor not only exhibited intense red emission but also showed high color quality. The Ozawa and Dexter energy-transfer theories were employed to calculate the theoretical quenching concentration and determine the concentration quenching mechanism. In addition, the activation energy of BaLa0.7Eu0.3MgNbO6 was calculated through the Arrhenius equation. A configurational coordinate diagram was used to explain the thermal quenching mechanism.

Original languageEnglish
Pages (from-to)1909-1915
Number of pages7
JournalCeramics International
Volume44
Issue number2
DOIs
StatePublished - 1 Feb 2018

Keywords

  • Double perovskite
  • High quenching concentration
  • Red phosphors
  • White light-emitting diodes

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