Synthesis of highly substituted 2-hydroxybenzophenones through skeletal clipping of 3-benzofuranones

Chuan Bao Zhang; Jiying Xu; Xiao Qing Wang; Yi Hang Deng; Pei Hao Dou; Wen Li Xu; Qiu Xia Han; Lili Zhao; Ji Ya Fu

doi:10.1039/d5cc00396b

Synthesis of highly substituted 2-hydroxybenzophenones through skeletal clipping of 3-benzofuranones

Chuan Bao Zhang, Jiying Xu, Xiao Qing Wang, Yi Hang Deng, Pei Hao Dou, Wen Li Xu, Qiu Xia Han, Lili Zhao, Ji Ya Fu

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The transition-metal-free synthesis of 2-hydroxybenzophenones was achieved through skeletal clipping of 3-benzofuranones via annulation, ring clipping and a benzannulation process under mild conditions. More importantly, these compounds were evaluated for their antifungal activities in pesticide chemistry. Additionally, theoretical calculations were conducted on the key transition states.

Original language	English
Pages (from-to)	5645-5648
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	30
DOIs	https://doi.org/10.1039/d5cc00396b
State	Published - 12 Mar 2025

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abstract = "The transition-metal-free synthesis of 2-hydroxybenzophenones was achieved through skeletal clipping of 3-benzofuranones via annulation, ring clipping and a benzannulation process under mild conditions. More importantly, these compounds were evaluated for their antifungal activities in pesticide chemistry. Additionally, theoretical calculations were conducted on the key transition states.",

author = "Zhang, {Chuan Bao} and Jiying Xu and Wang, {Xiao Qing} and Deng, {Yi Hang} and Dou, {Pei Hao} and Xu, {Wen Li} and Han, {Qiu Xia} and Lili Zhao and Fu, {Ji Ya}",

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AU - Zhang, Chuan Bao

AU - Xu, Jiying

AU - Wang, Xiao Qing

AU - Deng, Yi Hang

AU - Dou, Pei Hao

AU - Xu, Wen Li

AU - Han, Qiu Xia

AU - Zhao, Lili

AU - Fu, Ji Ya

PY - 2025/3/12

Y1 - 2025/3/12

N2 - The transition-metal-free synthesis of 2-hydroxybenzophenones was achieved through skeletal clipping of 3-benzofuranones via annulation, ring clipping and a benzannulation process under mild conditions. More importantly, these compounds were evaluated for their antifungal activities in pesticide chemistry. Additionally, theoretical calculations were conducted on the key transition states.

AB - The transition-metal-free synthesis of 2-hydroxybenzophenones was achieved through skeletal clipping of 3-benzofuranones via annulation, ring clipping and a benzannulation process under mild conditions. More importantly, these compounds were evaluated for their antifungal activities in pesticide chemistry. Additionally, theoretical calculations were conducted on the key transition states.

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U2 - 10.1039/d5cc00396b

DO - 10.1039/d5cc00396b

M3 - 文章

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SN - 1359-7345

VL - 61

SP - 5645

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JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

Synthesis of highly substituted 2-hydroxybenzophenones through skeletal clipping of 3-benzofuranones

Abstract

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