The reactivity of [Zn2Cp*2]: Trapping monovalent {.ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)4-a(ZnZnCp*) 4-a] (a=0, 2)

Timo Bollermann; Kerstin Freitag; Christian Gemel; Rüdiger W. Seidel; Moritz Von Hopffgarten; Gernot Frenking; Roland A. Fischer

doi:10.1002/anie.201005808

The reactivity of [Zn₂Cp₂]: Trapping monovalent {^.ZnZnCp} in the metal-rich compounds [(Pd,Pt)(GaCp)_a(ZnCp)_4-a(ZnZnCp*) _4-a] (a=0, 2)

Timo Bollermann, Kerstin Freitag, Christian Gemel, Rüdiger W. Seidel, Moritz Von Hopffgarten, Gernot Frenking, Roland A. Fischer

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Inseparable zinc pair: The reaction of homoleptic {GaCp*}-containing compounds [M(GaCp*)₄] (M=Pd, Pt; Cp*=Me₅C ₅) with [Zn₂Cp*₂] leads to the formation of [M(GaCp*)₂(ZnCp*)₂(ZnZnCp*) ₂] (see picture: C gray, Ga yellow, Zn green, Pd blue) and [M(ZnCp*)₄(ZnZnCp*)₄]. Both molecules involve the novel zinc ligand system {ZnZnCp*}, which contains an intact Zn-Zn bond.

Original language	English
Pages (from-to)	772-776
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	3
DOIs	https://doi.org/10.1002/anie.201005808
State	Published - 17 Jan 2011
Externally published	Yes

Keywords

carbenoids
cluster compounds
density functional calculations
gallium
zinc

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title = "The reactivity of [Zn2Cp*2]: Trapping monovalent {.ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)4-a(ZnZnCp*) 4-a] (a=0, 2)",

abstract = "Inseparable zinc pair: The reaction of homoleptic {GaCp*}-containing compounds [M(GaCp*)4] (M=Pd, Pt; Cp*=Me5C 5) with [Zn2Cp*2] leads to the formation of [M(GaCp*)2(ZnCp*)2(ZnZnCp*) 2] (see picture: C gray, Ga yellow, Zn green, Pd blue) and [M(ZnCp*)4(ZnZnCp*)4]. Both molecules involve the novel zinc ligand system {ZnZnCp*}, which contains an intact Zn-Zn bond.",

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author = "Timo Bollermann and Kerstin Freitag and Christian Gemel and Seidel, {R{\"u}diger W.} and {Von Hopffgarten}, Moritz and Gernot Frenking and Fischer, {Roland A.}",

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doi = "10.1002/anie.201005808",

language = "英语",

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pages = "772--776",

journal = "Angewandte Chemie - International Edition",

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T2 - Trapping monovalent {.ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)4-a(ZnZnCp*) 4-a] (a=0, 2)

AU - Bollermann, Timo

AU - Freitag, Kerstin

AU - Gemel, Christian

AU - Seidel, Rüdiger W.

AU - Von Hopffgarten, Moritz

AU - Frenking, Gernot

AU - Fischer, Roland A.

PY - 2011/1/17

Y1 - 2011/1/17

N2 - Inseparable zinc pair: The reaction of homoleptic {GaCp*}-containing compounds [M(GaCp*)4] (M=Pd, Pt; Cp*=Me5C 5) with [Zn2Cp*2] leads to the formation of [M(GaCp*)2(ZnCp*)2(ZnZnCp*) 2] (see picture: C gray, Ga yellow, Zn green, Pd blue) and [M(ZnCp*)4(ZnZnCp*)4]. Both molecules involve the novel zinc ligand system {ZnZnCp*}, which contains an intact Zn-Zn bond.

AB - Inseparable zinc pair: The reaction of homoleptic {GaCp*}-containing compounds [M(GaCp*)4] (M=Pd, Pt; Cp*=Me5C 5) with [Zn2Cp*2] leads to the formation of [M(GaCp*)2(ZnCp*)2(ZnZnCp*) 2] (see picture: C gray, Ga yellow, Zn green, Pd blue) and [M(ZnCp*)4(ZnZnCp*)4]. Both molecules involve the novel zinc ligand system {ZnZnCp*}, which contains an intact Zn-Zn bond.

KW - carbenoids

KW - cluster compounds

KW - density functional calculations

KW - gallium

KW - zinc

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The reactivity of [Zn₂Cp₂]: Trapping monovalent {^.ZnZnCp} in the metal-rich compounds [(Pd,Pt)(GaCp)_a(ZnCp)_4-a(ZnZnCp*) _4-a] (a=0, 2)

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Keywords

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