1-(3-Fluorobenzyl)pyridinium bis(maleonitriledithiolato- κ2S,S′)nickelate(III) acetonitrile solvate

Hui Zhang; Xiao Ming Ren; Jing Li Xie; Yi Zhi Li; Qing Jin Meng

doi:10.1107/S1600536804014060

1-(3-Fluorobenzyl)pyridinium bis(maleonitriledithiolato- κ²S,S′)nickelate(III) acetonitrile solvate

Hui Zhang, Xiao Ming Ren, Jing Li Xie, Yi Zhi Li, Qing Jin Meng

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In the title compound, (C₁₂H₁₁FN)[Ni(C ₄N₂S₂)₂]·C₂H ₂N, completely segregated columnar stacks of anions and cations are observed. The anion columns have identical Ni⋯Ni distances of 4.2874 (9) Å. Within the cation columns, the benzene rings are parallel to each other;, however the centre-to-centre distance between adjacent aromatic rings is more than 4.2 Å, and so no π-π stacking interactions are found.

Original language	English
Pages (from-to)	m960-m962
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	7
DOIs	https://doi.org/10.1107/S1600536804014060
State	Published - Jul 2004
Externally published	Yes

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title = "1-(3-Fluorobenzyl)pyridinium bis(maleonitriledithiolato- κ2S,S′)nickelate(III) acetonitrile solvate",

abstract = "In the title compound, (C12H11FN)[Ni(C 4N2S2)2]·C2H 2N, completely segregated columnar stacks of anions and cations are observed. The anion columns have identical Ni⋯Ni distances of 4.2874 (9) {\AA}. Within the cation columns, the benzene rings are parallel to each other;, however the centre-to-centre distance between adjacent aromatic rings is more than 4.2 {\AA}, and so no π-π stacking interactions are found.",

author = "Hui Zhang and Ren, {Xiao Ming} and Xie, {Jing Li} and Li, {Yi Zhi} and Meng, {Qing Jin}",

year = "2004",

month = jul,

doi = "10.1107/S1600536804014060",

language = "英语",

volume = "60",

pages = "m960--m962",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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TY - JOUR

T1 - 1-(3-Fluorobenzyl)pyridinium bis(maleonitriledithiolato- κ2S,S′)nickelate(III) acetonitrile solvate

AU - Zhang, Hui

AU - Ren, Xiao Ming

AU - Xie, Jing Li

AU - Li, Yi Zhi

AU - Meng, Qing Jin

PY - 2004/7

Y1 - 2004/7

N2 - In the title compound, (C12H11FN)[Ni(C 4N2S2)2]·C2H 2N, completely segregated columnar stacks of anions and cations are observed. The anion columns have identical Ni⋯Ni distances of 4.2874 (9) Å. Within the cation columns, the benzene rings are parallel to each other;, however the centre-to-centre distance between adjacent aromatic rings is more than 4.2 Å, and so no π-π stacking interactions are found.

AB - In the title compound, (C12H11FN)[Ni(C 4N2S2)2]·C2H 2N, completely segregated columnar stacks of anions and cations are observed. The anion columns have identical Ni⋯Ni distances of 4.2874 (9) Å. Within the cation columns, the benzene rings are parallel to each other;, however the centre-to-centre distance between adjacent aromatic rings is more than 4.2 Å, and so no π-π stacking interactions are found.

UR - http://www.scopus.com/inward/record.url?scp=18444390298&partnerID=8YFLogxK

U2 - 10.1107/S1600536804014060

DO - 10.1107/S1600536804014060

M3 - 文章

AN - SCOPUS:18444390298

SN - 1600-5368

VL - 60

SP - m960-m962

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

1-(3-Fluorobenzyl)pyridinium bis(maleonitriledithiolato- κ²S,S′)nickelate(III) acetonitrile solvate

Abstract

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