3-{[Bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5methylbenzaldehyde

Ruo Xu Wang; Da Zhi Gao; Fan Ye; Yan Fei Wu; Dun Ru Zhu

doi:10.1107/S1600536812019940

3-{[Bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5methylbenzaldehyde

Ruo Xu Wang, Da Zhi Gao, Fan Ye, Yan Fei Wu, Dun Ru Zhu

COLLEGE OF CHEMICAL ENGINEERING

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In the title compound, C₂₁H₂₁N₃O ₂, the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The molecular conformation is stabilized by intramolecular bifurcated O - H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C - H⋯N hydrogen bonds.

Original language	English
Pages (from-to)	o1672-o1673
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	6
DOIs	https://doi.org/10.1107/S1600536812019940
State	Published - Jun 2012

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title = "3-{[Bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5methylbenzaldehyde",

abstract = "In the title compound, C21H21N3O 2, the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The molecular conformation is stabilized by intramolecular bifurcated O - H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C - H⋯N hydrogen bonds.",

author = "Wang, {Ruo Xu} and Gao, {Da Zhi} and Fan Ye and Wu, {Yan Fei} and Zhu, {Dun Ru}",

year = "2012",

month = jun,

doi = "10.1107/S1600536812019940",

language = "英语",

volume = "68",

pages = "o1672--o1673",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - 3-{[Bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5methylbenzaldehyde

AU - Wang, Ruo Xu

AU - Gao, Da Zhi

AU - Ye, Fan

AU - Wu, Yan Fei

AU - Zhu, Dun Ru

PY - 2012/6

Y1 - 2012/6

N2 - In the title compound, C21H21N3O 2, the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The molecular conformation is stabilized by intramolecular bifurcated O - H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C - H⋯N hydrogen bonds.

AB - In the title compound, C21H21N3O 2, the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The molecular conformation is stabilized by intramolecular bifurcated O - H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C - H⋯N hydrogen bonds.

UR - http://www.scopus.com/inward/record.url?scp=84862291382&partnerID=8YFLogxK

U2 - 10.1107/S1600536812019940

DO - 10.1107/S1600536812019940

M3 - 文章

AN - SCOPUS:84862291382

SN - 1600-5368

VL - 68

SP - o1672-o1673

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

3-{[Bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5methylbenzaldehyde

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