TY - JOUR
T1 - (9S,13R,14R)-7,8-Didehydro-3,4,7-trimeth-oxy-17-methyl-morphinan-6-one
AU - Li, Yu Feng
AU - Qian, Yi
AU - Yin, Li He
AU - Lv, Ran
AU - Zhu, Hong Jun
PY - 2009
Y1 - 2009
N2 - The title compound, C20H25NO4, was synthesized by a Mitsunobu reaction of sinomenine [(9S,13R,14R)-7,8-didehydro-4- hydroxy-3,7-dimethoxy-17-methylmorphinan-6-one] with methanol. The chiral centers were unchanged during the reaction. Intra-molecular C - H⋯O hydrogen bonds result in the formation of six-membered rings.
AB - The title compound, C20H25NO4, was synthesized by a Mitsunobu reaction of sinomenine [(9S,13R,14R)-7,8-didehydro-4- hydroxy-3,7-dimethoxy-17-methylmorphinan-6-one] with methanol. The chiral centers were unchanged during the reaction. Intra-molecular C - H⋯O hydrogen bonds result in the formation of six-membered rings.
UR - http://www.scopus.com/inward/record.url?scp=64149083159&partnerID=8YFLogxK
U2 - 10.1107/S1600536808040749
DO - 10.1107/S1600536808040749
M3 - 文章
AN - SCOPUS:64149083159
SN - 1600-5368
VL - 65
SP - o689
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 4
ER -