A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: Synthesis, crystal structure and magnetic properties

Guang Xiang Liu; Xiao Ming Ren; Heng Xu; Sadafumi Nishihara; Rong Yi Huang

doi:10.1016/j.inoche.2009.07.012

A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: Synthesis, crystal structure and magnetic properties

Guang Xiang Liu, Xiao Ming Ren, Heng Xu, Sadafumi Nishihara, Rong Yi Huang

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A novel heterometallic coordination polymer, [AgGd(PDC)₂]·2H₂O (1) (H₂PDC = pyridine-3,5-dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features an unusual three-dimensional network structure in which infinite gadolinium-carboxylate chains are linked by [Ag(PDC)₂]^3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties and magnetic properties of 1 have also been investigated.

Original language	English
Pages (from-to)	895-897
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	9
DOIs	https://doi.org/10.1016/j.inoche.2009.07.012
State	Published - Sep 2009
Externally published	Yes

Keywords

Crystal structure
Heterometallic coordination polymer
Luminescence
Magnetism

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10.1016/j.inoche.2009.07.012

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title = "A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: Synthesis, crystal structure and magnetic properties",

abstract = "A novel heterometallic coordination polymer, [AgGd(PDC)2]·2H2O (1) (H2PDC = pyridine-3,5-dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features an unusual three-dimensional network structure in which infinite gadolinium-carboxylate chains are linked by [Ag(PDC)2]3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties and magnetic properties of 1 have also been investigated.",

keywords = "Crystal structure, Heterometallic coordination polymer, Luminescence, Magnetism",

author = "Liu, {Guang Xiang} and Ren, {Xiao Ming} and Heng Xu and Sadafumi Nishihara and Huang, {Rong Yi}",

year = "2009",

month = sep,

doi = "10.1016/j.inoche.2009.07.012",

language = "英语",

volume = "12",

pages = "895--897",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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T1 - A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid

T2 - Synthesis, crystal structure and magnetic properties

AU - Liu, Guang Xiang

AU - Ren, Xiao Ming

AU - Xu, Heng

AU - Nishihara, Sadafumi

AU - Huang, Rong Yi

PY - 2009/9

Y1 - 2009/9

N2 - A novel heterometallic coordination polymer, [AgGd(PDC)2]·2H2O (1) (H2PDC = pyridine-3,5-dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features an unusual three-dimensional network structure in which infinite gadolinium-carboxylate chains are linked by [Ag(PDC)2]3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties and magnetic properties of 1 have also been investigated.

AB - A novel heterometallic coordination polymer, [AgGd(PDC)2]·2H2O (1) (H2PDC = pyridine-3,5-dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features an unusual three-dimensional network structure in which infinite gadolinium-carboxylate chains are linked by [Ag(PDC)2]3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties and magnetic properties of 1 have also been investigated.

KW - Crystal structure

KW - Heterometallic coordination polymer

KW - Luminescence

KW - Magnetism

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U2 - 10.1016/j.inoche.2009.07.012

DO - 10.1016/j.inoche.2009.07.012

M3 - 文章

AN - SCOPUS:69249202444

SN - 1387-7003

VL - 12

SP - 895

EP - 897

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: Synthesis, crystal structure and magnetic properties

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Keywords

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