A bis(maleonitriledithiolato)nickelate charge-transfer salt with mixed stacks exhibiting novel non-ferroelectric-type dielectric phase transition and bistability

Yao Chen; Shun Ping Zhao; Jian Lan Liu; Wei Hua Ning; Xiao Mei Sun; Xiao Ming Ren

doi:10.1039/c3ra41607k

A bis(maleonitriledithiolato)nickelate charge-transfer salt with mixed stacks exhibiting novel non-ferroelectric-type dielectric phase transition and bistability

Yao Chen, Shun Ping Zhao, Jian Lan Liu, Wei Hua Ning, Xiao Mei Sun, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A charge-transfer salt consisting of 1,1′-dioctyl-4,4′- bipyridinium and bis(maleonitriledithiolato)nickelate is described. Its crystal is built from mixed stacks of the anion and cation, with the anions (A) and cations (C) adopting an ...ACAC... fashion within a stack. This salt shows a novel non-ferroelectric-type dielectric phase transition at around 324 K and bistability.

Original language	English
Pages (from-to)	9178-9181
Number of pages	4
Journal	RSC Advances
Volume	4
Issue number	18
DOIs	https://doi.org/10.1039/c3ra41607k
State	Published - 2014

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title = "A bis(maleonitriledithiolato)nickelate charge-transfer salt with mixed stacks exhibiting novel non-ferroelectric-type dielectric phase transition and bistability",

abstract = "A charge-transfer salt consisting of 1,1′-dioctyl-4,4′- bipyridinium and bis(maleonitriledithiolato)nickelate is described. Its crystal is built from mixed stacks of the anion and cation, with the anions (A) and cations (C) adopting an ...ACAC... fashion within a stack. This salt shows a novel non-ferroelectric-type dielectric phase transition at around 324 K and bistability.",

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AU - Chen, Yao

AU - Zhao, Shun Ping

AU - Liu, Jian Lan

AU - Ning, Wei Hua

AU - Sun, Xiao Mei

AU - Ren, Xiao Ming

PY - 2014

Y1 - 2014

N2 - A charge-transfer salt consisting of 1,1′-dioctyl-4,4′- bipyridinium and bis(maleonitriledithiolato)nickelate is described. Its crystal is built from mixed stacks of the anion and cation, with the anions (A) and cations (C) adopting an ...ACAC... fashion within a stack. This salt shows a novel non-ferroelectric-type dielectric phase transition at around 324 K and bistability.

AB - A charge-transfer salt consisting of 1,1′-dioctyl-4,4′- bipyridinium and bis(maleonitriledithiolato)nickelate is described. Its crystal is built from mixed stacks of the anion and cation, with the anions (A) and cations (C) adopting an ...ACAC... fashion within a stack. This salt shows a novel non-ferroelectric-type dielectric phase transition at around 324 K and bistability.

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DO - 10.1039/c3ra41607k

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ER -

A bis(maleonitriledithiolato)nickelate charge-transfer salt with mixed stacks exhibiting novel non-ferroelectric-type dielectric phase transition and bistability

Abstract

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