A family of rare earth porous coordination polymers with different flexibility for CO2/C2H4 and CO 2/C2H6 separation

Jingui Duan; Masakazu Higuchi; Maw Lin Foo; Satoshi Horike; Koya Prabhakara Rao; Susumu Kitagawa

doi:10.1021/ic401157n

A family of rare earth porous coordination polymers with different flexibility for CO₂/C₂H₄ and CO ₂/C₂H₆ separation

Jingui Duan, Masakazu Higuchi, Maw Lin Foo, Satoshi Horike, Koya Prabhakara Rao, Susumu Kitagawa

Research output: Contribution to journal › Article › peer-review

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Abstract

A family of new porous coordination polymers (PCPs) were prepared by the reaction of an acylamide modified ligand (H₃L) and RE(NO) ₃·xH₂O (RE = Y, La, Ce, Nd, Eu, Tb, Dy, Ho, and Tm). PXRD and single-crystal X-ray analyses of them revealed that, besides the La PCP, all other rare earth members gave isomorphous structures. The two types of structural toplogies obtained, although similar, differ in their alignment of acylamide functional groups and structural flexibility. Adsorption experiments and in situ DRIFT spectra showed that rigid frameworks have the typical microporous behavior and poor selective capture of CO₂ over C ₂H₄ and C₂H₆; however, the unique La-PCP with structural flexibility and close-packed acylamide groups has a high selective capture of CO₂ with respect to C₂H₆ or C₂H₄ at 273 K, especially at the ambient pressure area (0.1-1 bar).

Original language	English
Pages (from-to)	8244-8249
Number of pages	6
Journal	Inorganic Chemistry
Volume	52
Issue number	14
DOIs	https://doi.org/10.1021/ic401157n
State	Published - 15 Jul 2013
Externally published	Yes

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title = "A family of rare earth porous coordination polymers with different flexibility for CO2/C2H4 and CO 2/C2H6 separation",

abstract = "A family of new porous coordination polymers (PCPs) were prepared by the reaction of an acylamide modified ligand (H3L) and RE(NO) 3·xH2O (RE = Y, La, Ce, Nd, Eu, Tb, Dy, Ho, and Tm). PXRD and single-crystal X-ray analyses of them revealed that, besides the La PCP, all other rare earth members gave isomorphous structures. The two types of structural toplogies obtained, although similar, differ in their alignment of acylamide functional groups and structural flexibility. Adsorption experiments and in situ DRIFT spectra showed that rigid frameworks have the typical microporous behavior and poor selective capture of CO2 over C 2H4 and C2H6; however, the unique La-PCP with structural flexibility and close-packed acylamide groups has a high selective capture of CO2 with respect to C2H6 or C2H4 at 273 K, especially at the ambient pressure area (0.1-1 bar).",

author = "Jingui Duan and Masakazu Higuchi and Foo, {Maw Lin} and Satoshi Horike and Rao, {Koya Prabhakara} and Susumu Kitagawa",

year = "2013",

month = jul,

day = "15",

doi = "10.1021/ic401157n",

language = "英语",

volume = "52",

pages = "8244--8249",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - A family of rare earth porous coordination polymers with different flexibility for CO2/C2H4 and CO 2/C2H6 separation

AU - Duan, Jingui

AU - Higuchi, Masakazu

AU - Foo, Maw Lin

AU - Horike, Satoshi

AU - Rao, Koya Prabhakara

AU - Kitagawa, Susumu

PY - 2013/7/15

Y1 - 2013/7/15

N2 - A family of new porous coordination polymers (PCPs) were prepared by the reaction of an acylamide modified ligand (H3L) and RE(NO) 3·xH2O (RE = Y, La, Ce, Nd, Eu, Tb, Dy, Ho, and Tm). PXRD and single-crystal X-ray analyses of them revealed that, besides the La PCP, all other rare earth members gave isomorphous structures. The two types of structural toplogies obtained, although similar, differ in their alignment of acylamide functional groups and structural flexibility. Adsorption experiments and in situ DRIFT spectra showed that rigid frameworks have the typical microporous behavior and poor selective capture of CO2 over C 2H4 and C2H6; however, the unique La-PCP with structural flexibility and close-packed acylamide groups has a high selective capture of CO2 with respect to C2H6 or C2H4 at 273 K, especially at the ambient pressure area (0.1-1 bar).

AB - A family of new porous coordination polymers (PCPs) were prepared by the reaction of an acylamide modified ligand (H3L) and RE(NO) 3·xH2O (RE = Y, La, Ce, Nd, Eu, Tb, Dy, Ho, and Tm). PXRD and single-crystal X-ray analyses of them revealed that, besides the La PCP, all other rare earth members gave isomorphous structures. The two types of structural toplogies obtained, although similar, differ in their alignment of acylamide functional groups and structural flexibility. Adsorption experiments and in situ DRIFT spectra showed that rigid frameworks have the typical microporous behavior and poor selective capture of CO2 over C 2H4 and C2H6; however, the unique La-PCP with structural flexibility and close-packed acylamide groups has a high selective capture of CO2 with respect to C2H6 or C2H4 at 273 K, especially at the ambient pressure area (0.1-1 bar).

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U2 - 10.1021/ic401157n

DO - 10.1021/ic401157n

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SN - 0020-1669

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SP - 8244

EP - 8249

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

A family of rare earth porous coordination polymers with different flexibility for CO₂/C₂H₄ and CO ₂/C₂H₆ separation

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