A Free Tetrazolyl Decorated Metal-Organic Framework Exhibiting High and Selective CO2 Adsorption

Zhiyong Lu; Fei Meng; Liting Du; Wenyun Jiang; Haifei Cao; Jingui Duan; Huajie Huang; Haiyan He

doi:10.1021/acs.inorgchem.8b02031

A Free Tetrazolyl Decorated Metal-Organic Framework Exhibiting High and Selective CO₂ Adsorption

Zhiyong Lu, Fei Meng, Liting Du, Wenyun Jiang, Haifei Cao, Jingui Duan, Huajie Huang, Haiyan He

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

In this work, we employed a new tetrazolyl-functionalized ligand, 5-(1H-tetrazole-5-yl)-1,3-bis(3,5-dicarboxylphenyl)-benzene (H₅TBDPB), and successfully obtained an example of incorporating free tetrazolyl groups in transition-metal-based MOFs based upon an ideal MOF platform. With a BET surface area of 2070 m² g^-1, this new tetrazolyl-decorated MOF [Cu₆(TBDPB)₃(H₂O)₆]·9DMF·15H₂O (HHU-5, HHU for Hohai University) exhibits a high CO₂ adsorption capacity of 37.1 wt % at 1 bar and 273 K and high CO₂ separation capacity toward N₂ and CH₄ as well.

Original language	English
Pages (from-to)	14018-14022
Number of pages	5
Journal	Inorganic Chemistry
Volume	57
Issue number	22
DOIs	https://doi.org/10.1021/acs.inorgchem.8b02031
State	Published - 19 Nov 2018

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title = "A Free Tetrazolyl Decorated Metal-Organic Framework Exhibiting High and Selective CO2 Adsorption",

abstract = "In this work, we employed a new tetrazolyl-functionalized ligand, 5-(1H-tetrazole-5-yl)-1,3-bis(3,5-dicarboxylphenyl)-benzene (H5TBDPB), and successfully obtained an example of incorporating free tetrazolyl groups in transition-metal-based MOFs based upon an ideal MOF platform. With a BET surface area of 2070 m2 g-1, this new tetrazolyl-decorated MOF [Cu6(TBDPB)3(H2O)6]·9DMF·15H2O (HHU-5, HHU for Hohai University) exhibits a high CO2 adsorption capacity of 37.1 wt % at 1 bar and 273 K and high CO2 separation capacity toward N2 and CH4 as well.",

author = "Zhiyong Lu and Fei Meng and Liting Du and Wenyun Jiang and Haifei Cao and Jingui Duan and Huajie Huang and Haiyan He",

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T1 - A Free Tetrazolyl Decorated Metal-Organic Framework Exhibiting High and Selective CO2 Adsorption

AU - Lu, Zhiyong

AU - Meng, Fei

AU - Du, Liting

AU - Jiang, Wenyun

AU - Cao, Haifei

AU - Duan, Jingui

AU - Huang, Huajie

AU - He, Haiyan

PY - 2018/11/19

Y1 - 2018/11/19

N2 - In this work, we employed a new tetrazolyl-functionalized ligand, 5-(1H-tetrazole-5-yl)-1,3-bis(3,5-dicarboxylphenyl)-benzene (H5TBDPB), and successfully obtained an example of incorporating free tetrazolyl groups in transition-metal-based MOFs based upon an ideal MOF platform. With a BET surface area of 2070 m2 g-1, this new tetrazolyl-decorated MOF [Cu6(TBDPB)3(H2O)6]·9DMF·15H2O (HHU-5, HHU for Hohai University) exhibits a high CO2 adsorption capacity of 37.1 wt % at 1 bar and 273 K and high CO2 separation capacity toward N2 and CH4 as well.

AB - In this work, we employed a new tetrazolyl-functionalized ligand, 5-(1H-tetrazole-5-yl)-1,3-bis(3,5-dicarboxylphenyl)-benzene (H5TBDPB), and successfully obtained an example of incorporating free tetrazolyl groups in transition-metal-based MOFs based upon an ideal MOF platform. With a BET surface area of 2070 m2 g-1, this new tetrazolyl-decorated MOF [Cu6(TBDPB)3(H2O)6]·9DMF·15H2O (HHU-5, HHU for Hohai University) exhibits a high CO2 adsorption capacity of 37.1 wt % at 1 bar and 273 K and high CO2 separation capacity toward N2 and CH4 as well.

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U2 - 10.1021/acs.inorgchem.8b02031

DO - 10.1021/acs.inorgchem.8b02031

M3 - 文章

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AN - SCOPUS:85056167206

SN - 0020-1669

VL - 57

SP - 14018

EP - 14022

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

A Free Tetrazolyl Decorated Metal-Organic Framework Exhibiting High and Selective CO₂ Adsorption

Abstract

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