TY - JOUR
T1 - A microporous metal-organic framework with butynelene functionality for selective gas sorption
AU - Wang, Lifeng
AU - Zhai, Lu
AU - Ren, Xiaoming
AU - Zhang, Wenwei
PY - 2013
Y1 - 2013
N2 - A porous metal-organic framework {[Cu2(BBTC)(H 2O)2] · 2DMSO · 4H2O}n (Cu-BBTC, BBTC=1, 1′-buta-diynebenzene -3,3′,5,5′- tetracarboxylate; DMSO=dimethyl sulfoxide) was solvothermally synthesized from a tetracarboxylate ligand with butynelene functionality and structurally characterized. Cu-BBTC features a three-dimensional fof network with two types of cages, a small cage is about 14 Å in diameter and a large shows an ellipsoidal pore with about 14.2 × 22.6 Å in axes. The activated sample of Cu-BBTC, with Langmuir surface area of 1569 m2 g -1, exhibits selective gas adsorption behavior with respect to C 2H2/CH4 and CO2/CH2 at room temperature.
AB - A porous metal-organic framework {[Cu2(BBTC)(H 2O)2] · 2DMSO · 4H2O}n (Cu-BBTC, BBTC=1, 1′-buta-diynebenzene -3,3′,5,5′- tetracarboxylate; DMSO=dimethyl sulfoxide) was solvothermally synthesized from a tetracarboxylate ligand with butynelene functionality and structurally characterized. Cu-BBTC features a three-dimensional fof network with two types of cages, a small cage is about 14 Å in diameter and a large shows an ellipsoidal pore with about 14.2 × 22.6 Å in axes. The activated sample of Cu-BBTC, with Langmuir surface area of 1569 m2 g -1, exhibits selective gas adsorption behavior with respect to C 2H2/CH4 and CO2/CH2 at room temperature.
KW - Functionality
KW - Gas adsorption
KW - Microporous metal-organic frameworks
KW - Selective separation
KW - Tetracarboxylate ligand with butynelene
UR - http://www.scopus.com/inward/record.url?scp=84885610391&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2013.05.004
DO - 10.1016/j.jssc.2013.05.004
M3 - 文章
AN - SCOPUS:84885610391
SN - 0022-4596
VL - 204
SP - 53
EP - 58
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
ER -