A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols

Chenjie Zhu; Zhi Zhang; Weiwei Ding; Jingjing Xie; Yong Chen; Jinglan Wu; Xiaochun Chen; Hanjie Ying

doi:10.1039/c3gc42124d

A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols

Chenjie Zhu, Zhi Zhang, Weiwei Ding, Jingjing Xie, Yong Chen, Jinglan Wu, Xiaochun Chen, Hanjie Ying

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

With the aid of the highly active nitroxyl radical AZADO (2-azaadamantane N-oxyl), a simple method for the aerobic catalytic oxidation of alcohols is presented. The oxidations could typically proceed under practical ambient conditions (room temperature, air atmosphere, no moisture effect, metal-free, etc.) with a broad generality of the alcohol substrates, and especially for the oxidation of complex and highly functionalized alcohols. An ionic mechanism is proposed for the present system.

Original language	English
Pages (from-to)	1131-1138
Number of pages	8
Journal	Green Chemistry
Volume	16
Issue number	3
DOIs	https://doi.org/10.1039/c3gc42124d
State	Published - Mar 2014

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title = "A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols",

abstract = "With the aid of the highly active nitroxyl radical AZADO (2-azaadamantane N-oxyl), a simple method for the aerobic catalytic oxidation of alcohols is presented. The oxidations could typically proceed under practical ambient conditions (room temperature, air atmosphere, no moisture effect, metal-free, etc.) with a broad generality of the alcohol substrates, and especially for the oxidation of complex and highly functionalized alcohols. An ionic mechanism is proposed for the present system.",

author = "Chenjie Zhu and Zhi Zhang and Weiwei Ding and Jingjing Xie and Yong Chen and Jinglan Wu and Xiaochun Chen and Hanjie Ying",

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doi = "10.1039/c3gc42124d",

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T1 - A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols

AU - Zhu, Chenjie

AU - Zhang, Zhi

AU - Ding, Weiwei

AU - Xie, Jingjing

AU - Chen, Yong

AU - Wu, Jinglan

AU - Chen, Xiaochun

AU - Ying, Hanjie

PY - 2014/3

Y1 - 2014/3

N2 - With the aid of the highly active nitroxyl radical AZADO (2-azaadamantane N-oxyl), a simple method for the aerobic catalytic oxidation of alcohols is presented. The oxidations could typically proceed under practical ambient conditions (room temperature, air atmosphere, no moisture effect, metal-free, etc.) with a broad generality of the alcohol substrates, and especially for the oxidation of complex and highly functionalized alcohols. An ionic mechanism is proposed for the present system.

AB - With the aid of the highly active nitroxyl radical AZADO (2-azaadamantane N-oxyl), a simple method for the aerobic catalytic oxidation of alcohols is presented. The oxidations could typically proceed under practical ambient conditions (room temperature, air atmosphere, no moisture effect, metal-free, etc.) with a broad generality of the alcohol substrates, and especially for the oxidation of complex and highly functionalized alcohols. An ionic mechanism is proposed for the present system.

UR - http://www.scopus.com/inward/record.url?scp=84894609012&partnerID=8YFLogxK

U2 - 10.1039/c3gc42124d

DO - 10.1039/c3gc42124d

M3 - 文章

AN - SCOPUS:84894609012

SN - 1463-9262

VL - 16

SP - 1131

EP - 1138

JO - Green Chemistry

JF - Green Chemistry

IS - 3

ER -

A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols

Abstract

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