A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline

Guang Xiang Liu; Xiao Chun Zha; Yan Wang; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1007/s10904-010-9434-x

A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline

Guang Xiang Liu, Xiao Chun Zha, Yan Wang, Sadafumi Nishihara, Xiao Ming Ren

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A new chiral Cu(II) complex, Cu ₃(phen) ₃(H ₂O)(BTA) ₂·13H ₂O (1) (H ₃BTA = benzene-1,3,5-triacetate acid and phen = phenanthroline) has been prepared by solvothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in the chiral space group C2 and has similar one-dimensional chains, which are further bridged by μ ₂-H ₂O to form a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated.

Original language	English
Pages (from-to)	201-206
Number of pages	6
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	21
Issue number	1
DOIs	https://doi.org/10.1007/s10904-010-9434-x
State	Published - Mar 2011
Externally published	Yes

Keywords

Carboxylate
Copper (II) complex
Magnetic property
Nonlinear optical property

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10.1007/s10904-010-9434-x

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title = "A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline",

abstract = "A new chiral Cu(II) complex, Cu 3(phen) 3(H 2O)(BTA) 2·13H 2O (1) (H 3BTA = benzene-1,3,5-triacetate acid and phen = phenanthroline) has been prepared by solvothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in the chiral space group C2 and has similar one-dimensional chains, which are further bridged by μ 2-H 2O to form a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated.",

keywords = "Carboxylate, Copper (II) complex, Magnetic property, Nonlinear optical property",

author = "Liu, {Guang Xiang} and Zha, {Xiao Chun} and Yan Wang and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2011",

month = mar,

doi = "10.1007/s10904-010-9434-x",

language = "英语",

volume = "21",

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T1 - A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline

AU - Liu, Guang Xiang

AU - Zha, Xiao Chun

AU - Wang, Yan

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2011/3

Y1 - 2011/3

N2 - A new chiral Cu(II) complex, Cu 3(phen) 3(H 2O)(BTA) 2·13H 2O (1) (H 3BTA = benzene-1,3,5-triacetate acid and phen = phenanthroline) has been prepared by solvothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in the chiral space group C2 and has similar one-dimensional chains, which are further bridged by μ 2-H 2O to form a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated.

AB - A new chiral Cu(II) complex, Cu 3(phen) 3(H 2O)(BTA) 2·13H 2O (1) (H 3BTA = benzene-1,3,5-triacetate acid and phen = phenanthroline) has been prepared by solvothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in the chiral space group C2 and has similar one-dimensional chains, which are further bridged by μ 2-H 2O to form a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated.

KW - Carboxylate

KW - Copper (II) complex

KW - Magnetic property

KW - Nonlinear optical property

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DO - 10.1007/s10904-010-9434-x

M3 - 文章

AN - SCOPUS:79951515492

SN - 1574-1443

VL - 21

SP - 201

EP - 206

JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

IS - 1

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A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline

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Keywords

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