A new rhodamine derivative bearing benzothiazole and thiocarbonyl moieties as a highly selective fluorescent and colorimetric chemodosimeter for Hg 2+

Fang Wang; Seong Won Nam; Zhiqian Guo; Sungsu Park; Juyoung Yoon

doi:10.1016/j.snb.2011.11.070

A new rhodamine derivative bearing benzothiazole and thiocarbonyl moieties as a highly selective fluorescent and colorimetric chemodosimeter for Hg ²⁺

Fang Wang, Seong Won Nam, Zhiqian Guo, Sungsu Park, Juyoung Yoon

Ewha Womans University

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

A novel rhodamine-based sensor 1 was designed and synthesized, which bears thiospirolactam chromophore and benzomidazole moieties. Sensor 1 showed a selective fluorescence enhancement and colorimetric change for Hg ²⁺ in CH ₃CN-HEPES buffer (0.01 M, pH 7.4) (3:7, v/v). As high as 180-fold fluorescence enhancement was observed for Hg ²⁺, which was attributed to the selective spirolactam-ring opening process followed by subsequent desulfurization. Furthermore, chemodosimeter 1 was successfully applied to microfluidic device.

Original language	English
Pages (from-to)	948-953
Number of pages	6
Journal	Sensors and Actuators B: Chemical
Volume	161
Issue number	1
DOIs	https://doi.org/10.1016/j.snb.2011.11.070
State	Published - 3 Jan 2012
Externally published	Yes

Keywords

Colorimetric sensor
Fluorescent sensor
Mercury ion sensor
Microfluidic system
Rhodamine

Access to Document

10.1016/j.snb.2011.11.070

Cite this

@article{5a4f5f724b5b4be180f5ced6e92b5d49,

title = "A new rhodamine derivative bearing benzothiazole and thiocarbonyl moieties as a highly selective fluorescent and colorimetric chemodosimeter for Hg 2+ ",

abstract = "A novel rhodamine-based sensor 1 was designed and synthesized, which bears thiospirolactam chromophore and benzomidazole moieties. Sensor 1 showed a selective fluorescence enhancement and colorimetric change for Hg 2+ in CH 3CN-HEPES buffer (0.01 M, pH 7.4) (3:7, v/v). As high as 180-fold fluorescence enhancement was observed for Hg 2+, which was attributed to the selective spirolactam-ring opening process followed by subsequent desulfurization. Furthermore, chemodosimeter 1 was successfully applied to microfluidic device.",

keywords = "Colorimetric sensor, Fluorescent sensor, Mercury ion sensor, Microfluidic system, Rhodamine",

author = "Fang Wang and Nam, {Seong Won} and Zhiqian Guo and Sungsu Park and Juyoung Yoon",

year = "2012",

month = jan,

day = "3",

doi = "10.1016/j.snb.2011.11.070",

language = "英语",

volume = "161",

pages = "948--953",

journal = "Sensors and Actuators B: Chemical",

issn = "0925-4005",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - A new rhodamine derivative bearing benzothiazole and thiocarbonyl moieties as a highly selective fluorescent and colorimetric chemodosimeter for Hg 2+

AU - Wang, Fang

AU - Nam, Seong Won

AU - Guo, Zhiqian

AU - Park, Sungsu

AU - Yoon, Juyoung

PY - 2012/1/3

Y1 - 2012/1/3

N2 - A novel rhodamine-based sensor 1 was designed and synthesized, which bears thiospirolactam chromophore and benzomidazole moieties. Sensor 1 showed a selective fluorescence enhancement and colorimetric change for Hg 2+ in CH 3CN-HEPES buffer (0.01 M, pH 7.4) (3:7, v/v). As high as 180-fold fluorescence enhancement was observed for Hg 2+, which was attributed to the selective spirolactam-ring opening process followed by subsequent desulfurization. Furthermore, chemodosimeter 1 was successfully applied to microfluidic device.

AB - A novel rhodamine-based sensor 1 was designed and synthesized, which bears thiospirolactam chromophore and benzomidazole moieties. Sensor 1 showed a selective fluorescence enhancement and colorimetric change for Hg 2+ in CH 3CN-HEPES buffer (0.01 M, pH 7.4) (3:7, v/v). As high as 180-fold fluorescence enhancement was observed for Hg 2+, which was attributed to the selective spirolactam-ring opening process followed by subsequent desulfurization. Furthermore, chemodosimeter 1 was successfully applied to microfluidic device.

KW - Colorimetric sensor

KW - Fluorescent sensor

KW - Mercury ion sensor

KW - Microfluidic system

KW - Rhodamine

UR - http://www.scopus.com/inward/record.url?scp=84856216564&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2011.11.070

DO - 10.1016/j.snb.2011.11.070

M3 - 文章

AN - SCOPUS:84856216564

SN - 0925-4005

VL - 161

SP - 948

EP - 953

JO - Sensors and Actuators B: Chemical

JF - Sensors and Actuators B: Chemical

IS - 1

ER -

A new rhodamine derivative bearing benzothiazole and thiocarbonyl moieties as a highly selective fluorescent and colorimetric chemodosimeter for Hg ²⁺

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this