A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5- anions

Shuai Zhou; Hongxiang Wan; Gonghao Hu; Yu Zhang; Ying Liu; Hao Miao; Dunru Zhu; Yan Xu

doi:10.1039/c5dt01026h

A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [V^V(μ₃-O)₄V^IV₄O₅(SO₄)₄(en)]^5- anions

Shuai Zhou, Hongxiang Wan, Gonghao Hu, Yu Zhang, Ying Liu, Hao Miao, Dunru Zhu, Yan Xu

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A new vanadium sulfate, [H₂N(CH₃)₂]_19/3(en)[V₅O₅(μ₃-O)₄(SO₄)₄](SO₄)_2/3[HN(CH₃)₂]_2/31, constructed from novel umbrella-like [V^V(μ₃-O)₄V^IV₄O₅(SO₄)₄(en)]^5- anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.

Original language	English
Pages (from-to)	8605-8608
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	18
DOIs	https://doi.org/10.1039/c5dt01026h
State	Published - 14 May 2015

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abstract = "A new vanadium sulfate, [H2N(CH3)2]19/3(en)[V5O5(μ3-O)4(SO4)4](SO4)2/3[HN(CH3)2]2/31, constructed from novel umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5- anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.",

author = "Shuai Zhou and Hongxiang Wan and Gonghao Hu and Yu Zhang and Ying Liu and Hao Miao and Dunru Zhu and Yan Xu",

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T1 - A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5- anions

AU - Zhou, Shuai

AU - Wan, Hongxiang

AU - Hu, Gonghao

AU - Zhang, Yu

AU - Liu, Ying

AU - Miao, Hao

AU - Zhu, Dunru

AU - Xu, Yan

PY - 2015/5/14

Y1 - 2015/5/14

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AB - A new vanadium sulfate, [H2N(CH3)2]19/3(en)[V5O5(μ3-O)4(SO4)4](SO4)2/3[HN(CH3)2]2/31, constructed from novel umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5- anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.

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A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [V^V(μ₃-O)₄V^IV₄O₅(SO₄)₄(en)]^5- anions

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