A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles

Ting Zhang; Yongheng Lv; Zhenguo Zhang; Zhenhua Jia; Teck Peng Loh

doi:10.1021/acs.orglett.3c01449

A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles

Ting Zhang, Yongheng Lv, Zhenguo Zhang, Zhenhua Jia, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.

Original language	English
Pages (from-to)	4468-4472
Number of pages	5
Journal	Organic Letters
Volume	25
Issue number	24
DOIs	https://doi.org/10.1021/acs.orglett.3c01449
State	Published - 23 Jun 2023
Externally published	Yes

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10.1021/acs.orglett.3c01449

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title = "A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles",

abstract = "Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.",

author = "Ting Zhang and Yongheng Lv and Zhenguo Zhang and Zhenhua Jia and Loh, {Teck Peng}",

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AU - Zhang, Ting

AU - Lv, Yongheng

AU - Zhang, Zhenguo

AU - Jia, Zhenhua

AU - Loh, Teck Peng

PY - 2023/6/23

Y1 - 2023/6/23

N2 - Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.

AB - Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.

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U2 - 10.1021/acs.orglett.3c01449

DO - 10.1021/acs.orglett.3c01449

M3 - 文章

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AN - SCOPUS:85163559125

SN - 1523-7060

VL - 25

SP - 4468

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JO - Organic Letters

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ER -

A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles

Abstract

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