A trinuclear Cu(II) complex from the use of phenyl 2-pyridyl ketoxime: Structure and magnetic behavior

Guang Xiang Liu; Hao Yang; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1080/15533174.2010.492557

A trinuclear Cu(II) complex from the use of phenyl 2-pyridyl ketoxime: Structure and magnetic behavior

Guang Xiang Liu, Hao Yang, Sadafumi Nishihara, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The reaction of phenyl 2-pyridyl ketoxime (PhPyCNOH) with Cu(BF ₄)₂·6H₂O in methanol results in the trinuclear complex [Cu₃(OH)(PhpyCNO)₃(H ₂O)](BF₄)₂ (1), which has been characterized by elemental analyses, IR spectrum and single-crystal X-ray diffraction techniques. The structure of 1 exhibits a triangle of Cu(II) ions, centered by a triply bridging hydroxo ligand and with three edge-bridging oximate groups from the three PhPyCNO- ions. The Cu₃OH units have an average Cu-O distance of 1.962(4) A, an average Cu-Cu distance of 3.177(4) A, and an average Cu-O-Cu angle of 108.2(2) A. Variable-temperature magnetic susceptibility studies reveal an antiferromagnetically-coupled system showing antisymmetric exchange.

Original language	English
Pages (from-to)	421-424
Number of pages	4
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	40
Issue number	6
DOIs	https://doi.org/10.1080/15533174.2010.492557
State	Published - Jul 2010

Keywords

Cu(II) complex
crystal structure
magnetism
trinuclear complex

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10.1080/15533174.2010.492557

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title = "A trinuclear Cu(II) complex from the use of phenyl 2-pyridyl ketoxime: Structure and magnetic behavior",

abstract = "The reaction of phenyl 2-pyridyl ketoxime (PhPyCNOH) with Cu(BF 4)2·6H2O in methanol results in the trinuclear complex [Cu3(OH)(PhpyCNO)3(H 2O)](BF4)2 (1), which has been characterized by elemental analyses, IR spectrum and single-crystal X-ray diffraction techniques. The structure of 1 exhibits a triangle of Cu(II) ions, centered by a triply bridging hydroxo ligand and with three edge-bridging oximate groups from the three PhPyCNO- ions. The Cu3OH units have an average Cu-O distance of 1.962(4) A, an average Cu-Cu distance of 3.177(4) A, and an average Cu-O-Cu angle of 108.2(2) A. Variable-temperature magnetic susceptibility studies reveal an antiferromagnetically-coupled system showing antisymmetric exchange.",

keywords = "Cu(II) complex, crystal structure, magnetism, trinuclear complex",

author = "Liu, {Guang Xiang} and Hao Yang and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2010",

month = jul,

doi = "10.1080/15533174.2010.492557",

language = "英语",

volume = "40",

pages = "421--424",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

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T1 - A trinuclear Cu(II) complex from the use of phenyl 2-pyridyl ketoxime

T2 - Structure and magnetic behavior

AU - Liu, Guang Xiang

AU - Yang, Hao

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2010/7

Y1 - 2010/7

N2 - The reaction of phenyl 2-pyridyl ketoxime (PhPyCNOH) with Cu(BF 4)2·6H2O in methanol results in the trinuclear complex [Cu3(OH)(PhpyCNO)3(H 2O)](BF4)2 (1), which has been characterized by elemental analyses, IR spectrum and single-crystal X-ray diffraction techniques. The structure of 1 exhibits a triangle of Cu(II) ions, centered by a triply bridging hydroxo ligand and with three edge-bridging oximate groups from the three PhPyCNO- ions. The Cu3OH units have an average Cu-O distance of 1.962(4) A, an average Cu-Cu distance of 3.177(4) A, and an average Cu-O-Cu angle of 108.2(2) A. Variable-temperature magnetic susceptibility studies reveal an antiferromagnetically-coupled system showing antisymmetric exchange.

AB - The reaction of phenyl 2-pyridyl ketoxime (PhPyCNOH) with Cu(BF 4)2·6H2O in methanol results in the trinuclear complex [Cu3(OH)(PhpyCNO)3(H 2O)](BF4)2 (1), which has been characterized by elemental analyses, IR spectrum and single-crystal X-ray diffraction techniques. The structure of 1 exhibits a triangle of Cu(II) ions, centered by a triply bridging hydroxo ligand and with three edge-bridging oximate groups from the three PhPyCNO- ions. The Cu3OH units have an average Cu-O distance of 1.962(4) A, an average Cu-Cu distance of 3.177(4) A, and an average Cu-O-Cu angle of 108.2(2) A. Variable-temperature magnetic susceptibility studies reveal an antiferromagnetically-coupled system showing antisymmetric exchange.

KW - Cu(II) complex

KW - crystal structure

KW - magnetism

KW - trinuclear complex

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U2 - 10.1080/15533174.2010.492557

DO - 10.1080/15533174.2010.492557

M3 - 文章

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SN - 1553-3174

VL - 40

SP - 421

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JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

IS - 6

ER -

A trinuclear Cu(II) complex from the use of phenyl 2-pyridyl ketoxime: Structure and magnetic behavior

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Keywords

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