A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

Hai Rong Zhao; Chen Xue; Cui Ping Li; Kai Ming Zhang; Hong Bin Luo; Shao Xian Liu; Xiao Ming Ren

doi:10.1021/acs.inorgchem.6b01438

A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

Hai Rong Zhao, Chen Xue, Cui Ping Li, Kai Ming Zhang, Hong Bin Luo, Shao Xian Liu, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C₂H₁₀N₂)[Mn₂(HPO₄)₃](H₂O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn₃O₁₃ cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10^-3 S·cm^-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.

Original language	English
Pages (from-to)	8971-8975
Number of pages	5
Journal	Inorganic Chemistry
Volume	55
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01438
State	Published - 6 Sep 2016

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title = "A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature",

abstract = "The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C2H10N2)[Mn2(HPO4)3](H2O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn3O13 cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10-3 S·cm-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.",

author = "Zhao, {Hai Rong} and Chen Xue and Li, {Cui Ping} and Zhang, {Kai Ming} and Luo, {Hong Bin} and Liu, {Shao Xian} and Ren, {Xiao Ming}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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doi = "10.1021/acs.inorgchem.6b01438",

language = "英语",

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T1 - A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

AU - Zhao, Hai Rong

AU - Xue, Chen

AU - Li, Cui Ping

AU - Zhang, Kai Ming

AU - Luo, Hong Bin

AU - Liu, Shao Xian

AU - Ren, Xiao Ming

PY - 2016/9/6

Y1 - 2016/9/6

N2 - The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C2H10N2)[Mn2(HPO4)3](H2O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn3O13 cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10-3 S·cm-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.

AB - The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C2H10N2)[Mn2(HPO4)3](H2O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn3O13 cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10-3 S·cm-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

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