A water-stable open-framework zirconium(iv)phosphate and its water-assisted high proton conductivity

Jing Wei Yu; Hai Jiao Yu; Zhi Yuan Yao; Zi Han Li; Qiu Ren; Hong Bin Luo; Yang Zou; Lifeng Wang; Xiao Ming Ren

doi:10.1039/d1ce00852h

A water-stable open-framework zirconium(iv)phosphate and its water-assisted high proton conductivity

Jing Wei Yu, Hai Jiao Yu, Zhi Yuan Yao, Zi Han Li, Qiu Ren, Hong Bin Luo, Yang Zou, Lifeng Wang, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A water stable proton-conducting material (NH₄)₅[Zr₃(OH)₃F₆(PO₄)₂(HPO₄)] (ZrP) was hydrothermally synthesized. The three-dimensional (3D) framework ofZrPis composed of ZrF₂O₄octahedra and H_xPO₄phosphate units forming 18-ring channels through sharing oxygen atoms. Ammonium cations charge balance the anionic framework. Alternating current (AC) impedance measurements onZrPpowder samples show that at 25-60 °C and 98% relative humidity (RH), the proton conductivity is around 10⁻²S cm⁻¹, and the activation energy (E_a) is 0.33 eV.

Original language	English
Pages (from-to)	6093-6097
Number of pages	5
Journal	CrystEngComm
Volume	23
Issue number	35
DOIs	https://doi.org/10.1039/d1ce00852h
State	Published - 21 Sep 2021

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title = "A water-stable open-framework zirconium(iv)phosphate and its water-assisted high proton conductivity",

abstract = "A water stable proton-conducting material (NH4)5[Zr3(OH)3F6(PO4)2(HPO4)] (ZrP) was hydrothermally synthesized. The three-dimensional (3D) framework ofZrPis composed of ZrF2O4octahedra and HxPO4phosphate units forming 18-ring channels through sharing oxygen atoms. Ammonium cations charge balance the anionic framework. Alternating current (AC) impedance measurements onZrPpowder samples show that at 25-60 °C and 98% relative humidity (RH), the proton conductivity is around 10−2S cm−1, and the activation energy (Ea) is 0.33 eV.",

author = "Yu, {Jing Wei} and Yu, {Hai Jiao} and Yao, {Zhi Yuan} and Li, {Zi Han} and Qiu Ren and Luo, {Hong Bin} and Yang Zou and Lifeng Wang and Ren, {Xiao Ming}",

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month = sep,

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doi = "10.1039/d1ce00852h",

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volume = "23",

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TY - JOUR

T1 - A water-stable open-framework zirconium(iv)phosphate and its water-assisted high proton conductivity

AU - Yu, Jing Wei

AU - Yu, Hai Jiao

AU - Yao, Zhi Yuan

AU - Li, Zi Han

AU - Ren, Qiu

AU - Luo, Hong Bin

AU - Zou, Yang

AU - Wang, Lifeng

AU - Ren, Xiao Ming

PY - 2021/9/21

Y1 - 2021/9/21

N2 - A water stable proton-conducting material (NH4)5[Zr3(OH)3F6(PO4)2(HPO4)] (ZrP) was hydrothermally synthesized. The three-dimensional (3D) framework ofZrPis composed of ZrF2O4octahedra and HxPO4phosphate units forming 18-ring channels through sharing oxygen atoms. Ammonium cations charge balance the anionic framework. Alternating current (AC) impedance measurements onZrPpowder samples show that at 25-60 °C and 98% relative humidity (RH), the proton conductivity is around 10−2S cm−1, and the activation energy (Ea) is 0.33 eV.

AB - A water stable proton-conducting material (NH4)5[Zr3(OH)3F6(PO4)2(HPO4)] (ZrP) was hydrothermally synthesized. The three-dimensional (3D) framework ofZrPis composed of ZrF2O4octahedra and HxPO4phosphate units forming 18-ring channels through sharing oxygen atoms. Ammonium cations charge balance the anionic framework. Alternating current (AC) impedance measurements onZrPpowder samples show that at 25-60 °C and 98% relative humidity (RH), the proton conductivity is around 10−2S cm−1, and the activation energy (Ea) is 0.33 eV.

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U2 - 10.1039/d1ce00852h

DO - 10.1039/d1ce00852h

M3 - 文章

AN - SCOPUS:85114931202

SN - 1466-8033

VL - 23

SP - 6093

EP - 6097

JO - CrystEngComm

JF - CrystEngComm

IS - 35

ER -

A water-stable open-framework zirconium(iv)phosphate and its water-assisted high proton conductivity

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