A white light-emitting metal–organic framework solid solution with multi-stimuli responsiveness in luminescent sensing

Xin Sui; Qin Yu Zhu; Chen Yang Zhao; Qian Wen Zhang; Xu Sheng Gao; Xiao Ming Ren

doi:10.1016/j.poly.2024.117170

A white light-emitting metal–organic framework solid solution with multi-stimuli responsiveness in luminescent sensing

Xin Sui, Qin Yu Zhu, Chen Yang Zhao, Qian Wen Zhang, Xu Sheng Gao, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In this study, we introduced a white-light solid solution of RE-MOF, namely Tb_0.042Eu_0.050Y_0.908-PTC (H₃PTC=2, 4, 6-pyridine tricarboxylic acid), which exhibits outstanding chemical and thermal stability along with multiband luminescence. Luminescent sensing experiments demonstrate that Tb_0.042Eu_0.050Y_0.908-PTC, as a multi-response luminescent sensor, has low detection limits for detecting Fe³⁺, Norfloxacin (NFX) and Ciprofloxacin (CPFX) via luminescence color changes. These results highlight their potential for luminescent sensing applications. Furthermore, the mechanism of luminescence sensing was investigated by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS) and ultraviolet–visible (UV–vis) spectroscopy.

Original language	English
Article number	117170
Journal	Polyhedron
Volume	262
DOIs	https://doi.org/10.1016/j.poly.2024.117170
State	Published - 1 Nov 2024

Keywords

Luminescence sensing
Multi-stimuli responsiveness
RE-MOF solid solution
White light

Access to Document

10.1016/j.poly.2024.117170

Cite this

@article{b3a356eb09c3476ab115fec3c6278f11,

title = "A white light-emitting metal–organic framework solid solution with multi-stimuli responsiveness in luminescent sensing",

abstract = "In this study, we introduced a white-light solid solution of RE-MOF, namely Tb0.042Eu0.050Y0.908-PTC (H3PTC=2, 4, 6-pyridine tricarboxylic acid), which exhibits outstanding chemical and thermal stability along with multiband luminescence. Luminescent sensing experiments demonstrate that Tb0.042Eu0.050Y0.908-PTC, as a multi-response luminescent sensor, has low detection limits for detecting Fe3+, Norfloxacin (NFX) and Ciprofloxacin (CPFX) via luminescence color changes. These results highlight their potential for luminescent sensing applications. Furthermore, the mechanism of luminescence sensing was investigated by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS) and ultraviolet–visible (UV–vis) spectroscopy.",

keywords = "Luminescence sensing, Multi-stimuli responsiveness, RE-MOF solid solution, White light",

author = "Xin Sui and Zhu, {Qin Yu} and Zhao, {Chen Yang} and Zhang, {Qian Wen} and Gao, {Xu Sheng} and Ren, {Xiao Ming}",

note = "Publisher Copyright: {\textcopyright} 2024 Elsevier Ltd",

year = "2024",

month = nov,

day = "1",

doi = "10.1016/j.poly.2024.117170",

language = "英语",

volume = "262",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - A white light-emitting metal–organic framework solid solution with multi-stimuli responsiveness in luminescent sensing

AU - Sui, Xin

AU - Zhu, Qin Yu

AU - Zhao, Chen Yang

AU - Zhang, Qian Wen

AU - Gao, Xu Sheng

AU - Ren, Xiao Ming

PY - 2024/11/1

Y1 - 2024/11/1

N2 - In this study, we introduced a white-light solid solution of RE-MOF, namely Tb0.042Eu0.050Y0.908-PTC (H3PTC=2, 4, 6-pyridine tricarboxylic acid), which exhibits outstanding chemical and thermal stability along with multiband luminescence. Luminescent sensing experiments demonstrate that Tb0.042Eu0.050Y0.908-PTC, as a multi-response luminescent sensor, has low detection limits for detecting Fe3+, Norfloxacin (NFX) and Ciprofloxacin (CPFX) via luminescence color changes. These results highlight their potential for luminescent sensing applications. Furthermore, the mechanism of luminescence sensing was investigated by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS) and ultraviolet–visible (UV–vis) spectroscopy.

AB - In this study, we introduced a white-light solid solution of RE-MOF, namely Tb0.042Eu0.050Y0.908-PTC (H3PTC=2, 4, 6-pyridine tricarboxylic acid), which exhibits outstanding chemical and thermal stability along with multiband luminescence. Luminescent sensing experiments demonstrate that Tb0.042Eu0.050Y0.908-PTC, as a multi-response luminescent sensor, has low detection limits for detecting Fe3+, Norfloxacin (NFX) and Ciprofloxacin (CPFX) via luminescence color changes. These results highlight their potential for luminescent sensing applications. Furthermore, the mechanism of luminescence sensing was investigated by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS) and ultraviolet–visible (UV–vis) spectroscopy.

KW - Luminescence sensing

KW - Multi-stimuli responsiveness

KW - RE-MOF solid solution

KW - White light

UR - http://www.scopus.com/inward/record.url?scp=85200812032&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2024.117170

DO - 10.1016/j.poly.2024.117170

M3 - 文章

AN - SCOPUS:85200812032

SN - 0277-5387

VL - 262

JO - Polyhedron

JF - Polyhedron

M1 - 117170

ER -

A white light-emitting metal–organic framework solid solution with multi-stimuli responsiveness in luminescent sensing

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this