Activated carbon-catalyzed hydrogenation of polycyclic arenes

Lin Bing Sun; Zhi min Zong; Jia Hui Kou; Li Fang Zhang; Zhong Hai Ni; Gui Yun Yu; Hong Chen; Xian Yong Wei; Chul Wee Lee

doi:10.1021/ef049946a

Activated carbon-catalyzed hydrogenation of polycyclic arenes

Lin Bing Sun, Zhi min Zong, Jia Hui Kou, Li Fang Zhang, Zhong Hai Ni, Gui Yun Yu, Hong Chen, Xian Yong Wei, Chul Wee Lee

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34 Scopus citations

Abstract

Benzene and four polycyclic arenes (PAs) were used as substrates and their hydrogenation reactions were conducted over activated carbon (AC) at 300 °C to examine the relationship between their molecular structures and reactivities. The results show that the AC catalyzed the hydrogenation of the PAs selectively and that the reactivities of the arenes toward hydrogenation were dependent on the hydrogen-accepting abilities of the arenes and on the adsorption strengths of the arenes on the catalyst surface. The related mechanisms for hydrogen transfer were also discussed.

Original language	English
Pages (from-to)	1500-1504
Number of pages	5
Journal	Energy and Fuels
Volume	18
Issue number	5
DOIs	https://doi.org/10.1021/ef049946a
State	Published - Sep 2004
Externally published	Yes

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title = "Activated carbon-catalyzed hydrogenation of polycyclic arenes",

abstract = "Benzene and four polycyclic arenes (PAs) were used as substrates and their hydrogenation reactions were conducted over activated carbon (AC) at 300 °C to examine the relationship between their molecular structures and reactivities. The results show that the AC catalyzed the hydrogenation of the PAs selectively and that the reactivities of the arenes toward hydrogenation were dependent on the hydrogen-accepting abilities of the arenes and on the adsorption strengths of the arenes on the catalyst surface. The related mechanisms for hydrogen transfer were also discussed.",

author = "Sun, {Lin Bing} and Zong, {Zhi min} and Kou, {Jia Hui} and Zhang, {Li Fang} and Ni, {Zhong Hai} and Yu, {Gui Yun} and Hong Chen and Wei, {Xian Yong} and Lee, {Chul Wee}",

year = "2004",

month = sep,

doi = "10.1021/ef049946a",

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T1 - Activated carbon-catalyzed hydrogenation of polycyclic arenes

AU - Sun, Lin Bing

AU - Zong, Zhi min

AU - Kou, Jia Hui

AU - Zhang, Li Fang

AU - Ni, Zhong Hai

AU - Yu, Gui Yun

AU - Chen, Hong

AU - Wei, Xian Yong

AU - Lee, Chul Wee

PY - 2004/9

Y1 - 2004/9

N2 - Benzene and four polycyclic arenes (PAs) were used as substrates and their hydrogenation reactions were conducted over activated carbon (AC) at 300 °C to examine the relationship between their molecular structures and reactivities. The results show that the AC catalyzed the hydrogenation of the PAs selectively and that the reactivities of the arenes toward hydrogenation were dependent on the hydrogen-accepting abilities of the arenes and on the adsorption strengths of the arenes on the catalyst surface. The related mechanisms for hydrogen transfer were also discussed.

AB - Benzene and four polycyclic arenes (PAs) were used as substrates and their hydrogenation reactions were conducted over activated carbon (AC) at 300 °C to examine the relationship between their molecular structures and reactivities. The results show that the AC catalyzed the hydrogenation of the PAs selectively and that the reactivities of the arenes toward hydrogenation were dependent on the hydrogen-accepting abilities of the arenes and on the adsorption strengths of the arenes on the catalyst surface. The related mechanisms for hydrogen transfer were also discussed.

UR - http://www.scopus.com/inward/record.url?scp=4844222037&partnerID=8YFLogxK

U2 - 10.1021/ef049946a

DO - 10.1021/ef049946a

M3 - 文章

AN - SCOPUS:4844222037

SN - 0887-0624

VL - 18

SP - 1500

EP - 1504

JO - Energy and Fuels

JF - Energy and Fuels

IS - 5

ER -

Activated carbon-catalyzed hydrogenation of polycyclic arenes

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