Aerobic oxidation of aldehydes to acids in water with cyclic (alkyl)(amino)carbene copper under mild conditions

Songbo Xu; Xiaomin Zhang; Wenjie Xiong; Ping Li; Wentao Ma; Xingbang Hu; Youting Wu

doi:10.1039/d1cc04812k

Aerobic oxidation of aldehydes to acids in water with cyclic (alkyl)(amino)carbene copper under mild conditions

Songbo Xu, Xiaomin Zhang, Wenjie Xiong, Ping Li, Wentao Ma, Xingbang Hu, Youting Wu

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

In this work, cyclic (alkyl)(amino)carbene copper ((CAAC)Cu) catalyzed aerobic oxidation of aldehydes in water at room temperature has been reported. Good to excellent yields were obtained using different substrates. A possible reaction mechanism was proposed, in which (CAAC)Cu dioxygen activates the C-H bond of aldehyde with a low barrier of 10.6

Original language	English
Pages (from-to)	2132-2135
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	13
DOIs	https://doi.org/10.1039/d1cc04812k
State	Published - 14 Feb 2022
Externally published	Yes

Access to Document

10.1039/d1cc04812k

Cite this

@article{74cfe73c12014e7dad40c3077dfd4592,

title = "Aerobic oxidation of aldehydes to acids in water with cyclic (alkyl)(amino)carbene copper under mild conditions",

abstract = "In this work, cyclic (alkyl)(amino)carbene copper ((CAAC)Cu) catalyzed aerobic oxidation of aldehydes in water at room temperature has been reported. Good to excellent yields were obtained using different substrates. A possible reaction mechanism was proposed, in which (CAAC)Cu dioxygen activates the C-H bond of aldehyde with a low barrier of 10.6",

author = "Songbo Xu and Xiaomin Zhang and Wenjie Xiong and Ping Li and Wentao Ma and Xingbang Hu and Youting Wu",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry",

year = "2022",

month = feb,

day = "14",

doi = "10.1039/d1cc04812k",

language = "英语",

volume = "58",

pages = "2132--2135",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Aerobic oxidation of aldehydes to acids in water with cyclic (alkyl)(amino)carbene copper under mild conditions

AU - Xu, Songbo

AU - Zhang, Xiaomin

AU - Xiong, Wenjie

AU - Li, Ping

AU - Ma, Wentao

AU - Hu, Xingbang

AU - Wu, Youting

N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry

PY - 2022/2/14

Y1 - 2022/2/14

N2 - In this work, cyclic (alkyl)(amino)carbene copper ((CAAC)Cu) catalyzed aerobic oxidation of aldehydes in water at room temperature has been reported. Good to excellent yields were obtained using different substrates. A possible reaction mechanism was proposed, in which (CAAC)Cu dioxygen activates the C-H bond of aldehyde with a low barrier of 10.6

AB - In this work, cyclic (alkyl)(amino)carbene copper ((CAAC)Cu) catalyzed aerobic oxidation of aldehydes in water at room temperature has been reported. Good to excellent yields were obtained using different substrates. A possible reaction mechanism was proposed, in which (CAAC)Cu dioxygen activates the C-H bond of aldehyde with a low barrier of 10.6

UR - http://www.scopus.com/inward/record.url?scp=85124497610&partnerID=8YFLogxK

U2 - 10.1039/d1cc04812k

DO - 10.1039/d1cc04812k

M3 - 文章

C2 - 34704994

AN - SCOPUS:85124497610

SN - 1359-7345

VL - 58

SP - 2132

EP - 2135

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Aerobic oxidation of aldehydes to acids in water with cyclic (alkyl)(amino)carbene copper under mild conditions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this