AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process

Chengkou Liu; Zheng Fang; Zhao Yang; Qingwen Li; Shiyu Guo; Kai Guo

doi:10.1039/c5ob01834j

AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process

Chengkou Liu, Zheng Fang, Zhao Yang, Qingwen Li, Shiyu Guo, Kai Guo

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

An economic and practical AIBN-initiated aerobic oxidation system of benzylic alcohols, hetero aryl alcohols and allyl alcohols was developed for the first time. Moderate to excellent yields were obtained with a broad substrate scope. Moreover, a proposed mechanism of a radical process was assumed and confirmed by the key intermediate detected.

Original language	English
Pages (from-to)	577-581
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	14
Issue number	2
DOIs	https://doi.org/10.1039/c5ob01834j
State	Published - 2016

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title = "AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process",

abstract = "An economic and practical AIBN-initiated aerobic oxidation system of benzylic alcohols, hetero aryl alcohols and allyl alcohols was developed for the first time. Moderate to excellent yields were obtained with a broad substrate scope. Moreover, a proposed mechanism of a radical process was assumed and confirmed by the key intermediate detected.",

author = "Chengkou Liu and Zheng Fang and Zhao Yang and Qingwen Li and Shiyu Guo and Kai Guo",

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year = "2016",

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T1 - AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process

AU - Liu, Chengkou

AU - Fang, Zheng

AU - Yang, Zhao

AU - Li, Qingwen

AU - Guo, Shiyu

AU - Guo, Kai

PY - 2016

Y1 - 2016

N2 - An economic and practical AIBN-initiated aerobic oxidation system of benzylic alcohols, hetero aryl alcohols and allyl alcohols was developed for the first time. Moderate to excellent yields were obtained with a broad substrate scope. Moreover, a proposed mechanism of a radical process was assumed and confirmed by the key intermediate detected.

AB - An economic and practical AIBN-initiated aerobic oxidation system of benzylic alcohols, hetero aryl alcohols and allyl alcohols was developed for the first time. Moderate to excellent yields were obtained with a broad substrate scope. Moreover, a proposed mechanism of a radical process was assumed and confirmed by the key intermediate detected.

UR - http://www.scopus.com/inward/record.url?scp=84983113575&partnerID=8YFLogxK

U2 - 10.1039/c5ob01834j

DO - 10.1039/c5ob01834j

M3 - 文章

AN - SCOPUS:84983113575

SN - 1477-0520

VL - 14

SP - 577

EP - 581

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 2

ER -

AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process

Abstract

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