Alkali salt of L-proline as an efficient and practical catalyst for the cyanosilylation of a wide variety of carbonyl compounds under solvent-free conditions

Zhi Liang Shen; Shun Jun Ji

doi:10.1080/00397910802431149

Alkali salt of L-proline as an efficient and practical catalyst for the cyanosilylation of a wide variety of carbonyl compounds under solvent-free conditions

Zhi Liang Shen, Shun Jun Ji

Soochow University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The alkali salt of L-proline was demonstrated to be an efficient and practical catalyst for the cyanosilylation of a wide variety of simple and functionalized carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the corresponding cyanohydrins in good to excellent yields.

Original language	English
Pages (from-to)	775-791
Number of pages	17
Journal	Synthetic Communications
Volume	39
Issue number	5
DOIs	https://doi.org/10.1080/00397910802431149
State	Published - Jan 2009
Externally published	Yes

Keywords

Cyanohydrin
Cyanosilylation
L-proline salt
Solvent-free condition
TMSCN

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10.1080/00397910802431149

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abstract = "The alkali salt of L-proline was demonstrated to be an efficient and practical catalyst for the cyanosilylation of a wide variety of simple and functionalized carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the corresponding cyanohydrins in good to excellent yields.",

keywords = "Cyanohydrin, Cyanosilylation, L-proline salt, Solvent-free condition, TMSCN",

author = "Shen, {Zhi Liang} and Ji, {Shun Jun}",

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AU - Ji, Shun Jun

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N2 - The alkali salt of L-proline was demonstrated to be an efficient and practical catalyst for the cyanosilylation of a wide variety of simple and functionalized carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the corresponding cyanohydrins in good to excellent yields.

AB - The alkali salt of L-proline was demonstrated to be an efficient and practical catalyst for the cyanosilylation of a wide variety of simple and functionalized carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the corresponding cyanohydrins in good to excellent yields.

KW - Cyanohydrin

KW - Cyanosilylation

KW - L-proline salt

KW - Solvent-free condition

KW - TMSCN

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Alkali salt of L-proline as an efficient and practical catalyst for the cyanosilylation of a wide variety of carbonyl compounds under solvent-free conditions

Abstract

Keywords

Access to Document

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