TY - JOUR
T1 - Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
AU - Gu, Zhida
AU - Zhang, Wenlei
AU - Pan, Ting
AU - Shen, Yu
AU - Qin, Peishan
AU - Zhang, Peng
AU - Li, Xiaohan
AU - Liu, Liwei
AU - Li, Linjie
AU - Fu, Yu
AU - Zhang, Weina
AU - Huo, Fengwei
N1 - Publisher Copyright:
Copyright © 2021 Zhida Gu et al. Exclusive Licensee Science and Technology Review Publishing House. Distributed under a Creative Commons Attribution License (CC BY 4.0).
PY - 2021
Y1 - 2021
N2 - Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites.
AB - Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites.
UR - http://www.scopus.com/inward/record.url?scp=85122477904&partnerID=8YFLogxK
U2 - 10.34133/2021/9854946
DO - 10.34133/2021/9854946
M3 - 文章
AN - SCOPUS:85122477904
SN - 2096-5168
VL - 2021
JO - Research
JF - Research
M1 - 9854946
ER -