Approaching a stable, green twisted heteroacene through “clean reaction” strategy

Gang Li; Hieu M. Duong; Zhonghan Zhang; Jinchong Xiao; Lei Liu; Yanli Zhao; Hua Zhang; Fengwei Huo; Shuzhou Li; Jan Ma; Fred Wudl; Qichun Zhang

doi:10.1039/c2cc32048g

Approaching a stable, green twisted heteroacene through “clean reaction” strategy

Gang Li, Hieu M. Duong, Zhonghan Zhang, Jinchong Xiao, Lei Liu, Yanli Zhao, Hua Zhang, Fengwei Huo, Shuzhou Li, Jan Ma, Fred Wudl, Qichun Zhang

Research output: Contribution to journal › Article › peer-review

105 Scopus citations

Abstract

A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.

Original language	English
Pages (from-to)	5974-5976
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	48
DOIs	https://doi.org/10.1039/c2cc32048g
State	Published - 21 May 2012
Externally published	Yes

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title = "Approaching a stable, green twisted heteroacene through “clean reaction” strategy",

abstract = "A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.",

author = "Gang Li and Duong, {Hieu M.} and Zhonghan Zhang and Jinchong Xiao and Lei Liu and Yanli Zhao and Hua Zhang and Fengwei Huo and Shuzhou Li and Jan Ma and Fred Wudl and Qichun Zhang",

year = "2012",

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doi = "10.1039/c2cc32048g",

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T1 - Approaching a stable, green twisted heteroacene through “clean reaction” strategy

AU - Li, Gang

AU - Duong, Hieu M.

AU - Zhang, Zhonghan

AU - Xiao, Jinchong

AU - Liu, Lei

AU - Zhao, Yanli

AU - Zhang, Hua

AU - Huo, Fengwei

AU - Li, Shuzhou

AU - Ma, Jan

AU - Wudl, Fred

AU - Zhang, Qichun

PY - 2012/5/21

Y1 - 2012/5/21

N2 - A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.

AB - A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.

UR - http://www.scopus.com/inward/record.url?scp=84861637889&partnerID=8YFLogxK

U2 - 10.1039/c2cc32048g

DO - 10.1039/c2cc32048g

M3 - 文章

AN - SCOPUS:84861637889

SN - 1359-7345

VL - 48

SP - 5974

EP - 5976

JO - Chemical Communications

JF - Chemical Communications

IS - 48

ER -

Approaching a stable, green twisted heteroacene through “clean reaction” strategy

Abstract

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