Aqueous Organic Hydrogen Gas Proton Batteries with Ultrahigh-Rate and Ultralow-Temperature Performance

Shuang Liu; Song Jin; Taoli Jiang; Muhammad Sajid; Jingwen Xu; Kai Zhang; Yanpeng Fan; Qia Peng; Xinhua Zheng; Zehui Xie; Zaichun Liu; Zhengxin Zhu; Xiaoyang Wang; Qingshun Nian; Jinghao Chen; Ke Li; Chunyue Shen; Wei Chen

doi:10.1021/acs.nanolett.3c01304

Aqueous Organic Hydrogen Gas Proton Batteries with Ultrahigh-Rate and Ultralow-Temperature Performance

Shuang Liu, Song Jin, Taoli Jiang, Muhammad Sajid, Jingwen Xu, Kai Zhang, Yanpeng Fan, Qia Peng, Xinhua Zheng, Zehui Xie, Zaichun Liu, Zhengxin Zhu, Xiaoyang Wang, Qingshun Nian, Jinghao Chen, Ke Li, Chunyue Shen, Wei Chen

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Aqueous proton batteries (APBs) have emerged as one of the most promising batteries for large-scale energy storage technology. However, they usually show an undesirable electrochemical performance. Herein, we demonstrate a novel aqueous catalytic hydrogen gas powered organic proton (HOP) battery, which is driven by hydrogen evolution/oxidation redox reactions via commercial nanocatalysts on the anode and coordination/decoordination reactions of C═O with H⁺ on the cathode. The HOP battery shows an excellent rate capacity of 190.1 mAh g^-1 at 1 A g^-1 and 71.4 mAh g^-1 at 100 A g^-1. It also delivers a capacity of 96.6 mAh g^-1 after 100000 cycles and operates at temperatures down to −70 °C. Moreover, the HOP battery is fabricated in a large-scale pouch cell with an extended capacity, exhibiting its potential for practical energy storage applications. This work provides new insights into the building of sustainable APBs, which will broaden the horizons of high-performance aqueous batteries.

Original language	English
Pages (from-to)	9664-9671
Number of pages	8
Journal	Nano Letters
Volume	23
Issue number	20
DOIs	https://doi.org/10.1021/acs.nanolett.3c01304
State	Published - 25 Oct 2023
Externally published	Yes

Keywords

aqueous proton batteries
hydrogen gas batteries
organic proton batteries
ultrahigh rate capabilities
ultralong cycle life
ultralow-temperature operation

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10.1021/acs.nanolett.3c01304

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title = "Aqueous Organic Hydrogen Gas Proton Batteries with Ultrahigh-Rate and Ultralow-Temperature Performance",

abstract = "Aqueous proton batteries (APBs) have emerged as one of the most promising batteries for large-scale energy storage technology. However, they usually show an undesirable electrochemical performance. Herein, we demonstrate a novel aqueous catalytic hydrogen gas powered organic proton (HOP) battery, which is driven by hydrogen evolution/oxidation redox reactions via commercial nanocatalysts on the anode and coordination/decoordination reactions of C═O with H+ on the cathode. The HOP battery shows an excellent rate capacity of 190.1 mAh g-1 at 1 A g-1 and 71.4 mAh g-1 at 100 A g-1. It also delivers a capacity of 96.6 mAh g-1 after 100000 cycles and operates at temperatures down to −70 °C. Moreover, the HOP battery is fabricated in a large-scale pouch cell with an extended capacity, exhibiting its potential for practical energy storage applications. This work provides new insights into the building of sustainable APBs, which will broaden the horizons of high-performance aqueous batteries.",

keywords = "aqueous proton batteries, hydrogen gas batteries, organic proton batteries, ultrahigh rate capabilities, ultralong cycle life, ultralow-temperature operation",

author = "Shuang Liu and Song Jin and Taoli Jiang and Muhammad Sajid and Jingwen Xu and Kai Zhang and Yanpeng Fan and Qia Peng and Xinhua Zheng and Zehui Xie and Zaichun Liu and Zhengxin Zhu and Xiaoyang Wang and Qingshun Nian and Jinghao Chen and Ke Li and Chunyue Shen and Wei Chen",

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doi = "10.1021/acs.nanolett.3c01304",

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T1 - Aqueous Organic Hydrogen Gas Proton Batteries with Ultrahigh-Rate and Ultralow-Temperature Performance

AU - Liu, Shuang

AU - Jin, Song

AU - Jiang, Taoli

AU - Sajid, Muhammad

AU - Xu, Jingwen

AU - Zhang, Kai

AU - Fan, Yanpeng

AU - Peng, Qia

AU - Zheng, Xinhua

AU - Xie, Zehui

AU - Liu, Zaichun

AU - Zhu, Zhengxin

AU - Wang, Xiaoyang

AU - Nian, Qingshun

AU - Chen, Jinghao

AU - Li, Ke

AU - Shen, Chunyue

AU - Chen, Wei

PY - 2023/10/25

Y1 - 2023/10/25

N2 - Aqueous proton batteries (APBs) have emerged as one of the most promising batteries for large-scale energy storage technology. However, they usually show an undesirable electrochemical performance. Herein, we demonstrate a novel aqueous catalytic hydrogen gas powered organic proton (HOP) battery, which is driven by hydrogen evolution/oxidation redox reactions via commercial nanocatalysts on the anode and coordination/decoordination reactions of C═O with H+ on the cathode. The HOP battery shows an excellent rate capacity of 190.1 mAh g-1 at 1 A g-1 and 71.4 mAh g-1 at 100 A g-1. It also delivers a capacity of 96.6 mAh g-1 after 100000 cycles and operates at temperatures down to −70 °C. Moreover, the HOP battery is fabricated in a large-scale pouch cell with an extended capacity, exhibiting its potential for practical energy storage applications. This work provides new insights into the building of sustainable APBs, which will broaden the horizons of high-performance aqueous batteries.

AB - Aqueous proton batteries (APBs) have emerged as one of the most promising batteries for large-scale energy storage technology. However, they usually show an undesirable electrochemical performance. Herein, we demonstrate a novel aqueous catalytic hydrogen gas powered organic proton (HOP) battery, which is driven by hydrogen evolution/oxidation redox reactions via commercial nanocatalysts on the anode and coordination/decoordination reactions of C═O with H+ on the cathode. The HOP battery shows an excellent rate capacity of 190.1 mAh g-1 at 1 A g-1 and 71.4 mAh g-1 at 100 A g-1. It also delivers a capacity of 96.6 mAh g-1 after 100000 cycles and operates at temperatures down to −70 °C. Moreover, the HOP battery is fabricated in a large-scale pouch cell with an extended capacity, exhibiting its potential for practical energy storage applications. This work provides new insights into the building of sustainable APBs, which will broaden the horizons of high-performance aqueous batteries.

KW - aqueous proton batteries

KW - hydrogen gas batteries

KW - organic proton batteries

KW - ultrahigh rate capabilities

KW - ultralong cycle life

KW - ultralow-temperature operation

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U2 - 10.1021/acs.nanolett.3c01304

DO - 10.1021/acs.nanolett.3c01304

M3 - 文章

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SN - 1530-6984

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SP - 9664

EP - 9671

JO - Nano Letters

JF - Nano Letters

IS - 20

ER -

Aqueous Organic Hydrogen Gas Proton Batteries with Ultrahigh-Rate and Ultralow-Temperature Performance

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