Aqueous Rechargeable Battery Based on Zinc and a Composite of LiNi1/3Co1/3Mn1/3O2

Faxing Wang; Yu Liu; Xiaowei Wang; Zheng Chang; Yuping Wu; Rudolf Holze

doi:10.1002/celc.201500033

Aqueous Rechargeable Battery Based on Zinc and a Composite of LiNi_1/3Co_1/3Mn_1/3O₂

Faxing Wang, Yu Liu, Xiaowei Wang, Zheng Chang, Yuping Wu, Rudolf Holze

School of energy science and engineering

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

A composite of rod-shaped LiNi_1/3Co_1/3Mn_1/3O₂ with graphene nanosheets and multiwall carbon nanotubes (MWCNTs) is assembled by using a hydrothermal method. In the composite, LiNi_1/3Co_1/3Mn_1/3O₂ and MWCNTs are wrapped into graphene nanosheets. It exhibits better rate capability in comparison with plain LiNi_1/3Co_1/3Mn_1/3O₂ as a positive electrode for an aqueous rechargeable battery, using zinc as the negative electrode. The average charge and discharge voltages of this aqueous rechargeable battery are 1.80 and 1.65V, respectively. Based on the total weight of the electrode materials of the composite and Zn, its energy density can reach 154Whkg^-1, which is comparable with that of Ni-MH batteries. Its cycling behavior is satisfactory.

Original language	English
Pages (from-to)	1024-1030
Number of pages	7
Journal	ChemElectroChem
Volume	2
Issue number	7
DOIs	https://doi.org/10.1002/celc.201500033
State	Published - 15 Jul 2015

Keywords

1D rod structure
Aqueous rechargeable battery
Graphene
LiNiCoMnO
Zinc

Access to Document

10.1002/celc.201500033

Cite this

@article{94a203a31fd443f8b2dbf36792571e72,

title = "Aqueous Rechargeable Battery Based on Zinc and a Composite of LiNi1/3Co1/3Mn1/3O2",

abstract = "A composite of rod-shaped LiNi1/3Co1/3Mn1/3O2 with graphene nanosheets and multiwall carbon nanotubes (MWCNTs) is assembled by using a hydrothermal method. In the composite, LiNi1/3Co1/3Mn1/3O2 and MWCNTs are wrapped into graphene nanosheets. It exhibits better rate capability in comparison with plain LiNi1/3Co1/3Mn1/3O2 as a positive electrode for an aqueous rechargeable battery, using zinc as the negative electrode. The average charge and discharge voltages of this aqueous rechargeable battery are 1.80 and 1.65V, respectively. Based on the total weight of the electrode materials of the composite and Zn, its energy density can reach 154Whkg-1, which is comparable with that of Ni-MH batteries. Its cycling behavior is satisfactory.",

keywords = "1D rod structure, Aqueous rechargeable battery, Graphene, LiNiCoMnO, Zinc",

author = "Faxing Wang and Yu Liu and Xiaowei Wang and Zheng Chang and Yuping Wu and Rudolf Holze",

note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2015",

month = jul,

day = "15",

doi = "10.1002/celc.201500033",

language = "英语",

volume = "2",

pages = "1024--1030",

journal = "ChemElectroChem",

issn = "2196-0216",

publisher = "John Wiley and Sons Ltd",

number = "7",

}

TY - JOUR

T1 - Aqueous Rechargeable Battery Based on Zinc and a Composite of LiNi1/3Co1/3Mn1/3O2

AU - Wang, Faxing

AU - Liu, Yu

AU - Wang, Xiaowei

AU - Chang, Zheng

AU - Wu, Yuping

AU - Holze, Rudolf

PY - 2015/7/15

Y1 - 2015/7/15

N2 - A composite of rod-shaped LiNi1/3Co1/3Mn1/3O2 with graphene nanosheets and multiwall carbon nanotubes (MWCNTs) is assembled by using a hydrothermal method. In the composite, LiNi1/3Co1/3Mn1/3O2 and MWCNTs are wrapped into graphene nanosheets. It exhibits better rate capability in comparison with plain LiNi1/3Co1/3Mn1/3O2 as a positive electrode for an aqueous rechargeable battery, using zinc as the negative electrode. The average charge and discharge voltages of this aqueous rechargeable battery are 1.80 and 1.65V, respectively. Based on the total weight of the electrode materials of the composite and Zn, its energy density can reach 154Whkg-1, which is comparable with that of Ni-MH batteries. Its cycling behavior is satisfactory.

AB - A composite of rod-shaped LiNi1/3Co1/3Mn1/3O2 with graphene nanosheets and multiwall carbon nanotubes (MWCNTs) is assembled by using a hydrothermal method. In the composite, LiNi1/3Co1/3Mn1/3O2 and MWCNTs are wrapped into graphene nanosheets. It exhibits better rate capability in comparison with plain LiNi1/3Co1/3Mn1/3O2 as a positive electrode for an aqueous rechargeable battery, using zinc as the negative electrode. The average charge and discharge voltages of this aqueous rechargeable battery are 1.80 and 1.65V, respectively. Based on the total weight of the electrode materials of the composite and Zn, its energy density can reach 154Whkg-1, which is comparable with that of Ni-MH batteries. Its cycling behavior is satisfactory.

KW - 1D rod structure

KW - Aqueous rechargeable battery

KW - Graphene

KW - LiNiCoMnO

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=84938580872&partnerID=8YFLogxK

U2 - 10.1002/celc.201500033

DO - 10.1002/celc.201500033

M3 - 文章

AN - SCOPUS:84938580872

SN - 2196-0216

VL - 2

SP - 1024

EP - 1030

JO - ChemElectroChem

JF - ChemElectroChem

IS - 7

ER -

Aqueous Rechargeable Battery Based on Zinc and a Composite of LiNi_1/3Co_1/3Mn_1/3O₂

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this