Bimetallic Coordination Polymers {[ML] [FeII FeIII (ox)3] · 1.5H2O}infin with Layer Structure Syntheses, Spectra Characterization

You Cun Chen; Guang Xiang Liu; Hong Zhou; Xiao Ming Ren

Bimetallic Coordination Polymers {[ML] [Fe^II Fe^III (ox)₃] · 1.5H₂O}_infin with Layer Structure Syntheses, Spectra Characterization

You Cun Chen, Guang Xiang Liu, Hong Zhou, Xiao Ming Ren

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

Two new schiff base complexes, NiL(ClO₄)·2H₂O (1) and CuL(ClO₄)·4H₂O (2) {L was condensed from equation molar salicylaldehyde and diethylenetriamine} have been synthesized and characterized. Further, two new bimetallic coordination polymers, {[ML][Fe^IIFe^III (ox)₃] · 1.5H₂O}_∞ were synthesized and characterized, where ox^2- = oxalate, M=Ni²⁺ (3) or Cu²⁺ (4). The tested results of elementary analysis of coordination polymers (3) and (4) were according with the theoretical value, and the results of the IR indicated that the coordination of oxalate were bridgetype in compound (3) and (4). 2-D layer coordination polymers were synthesized by oxalate and Fe³⁺, Fe²⁺. The result of Mössbauer spectra of (3) and (4) in room temperature revealed that two different postural ferric ions were found in coordination polymer (3) and (4) ,and anions layer was formed by [Fe^II Fe^III (ox)₃]^- unit. The compounds of (3) and (4) were bimetallic coordination polymers.

Original language	English
Pages (from-to)	x16-812
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	22
Issue number	5
State	Published - 2002
Externally published	Yes

Keywords

Bridging oxalate
Coordination polymer
Spectra characterization
Synthesis

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title = "Bimetallic Coordination Polymers {[ML] [FeII FeIII (ox)3] · 1.5H2O}infin with Layer Structure Syntheses, Spectra Characterization",

abstract = "Two new schiff base complexes, NiL(ClO4)·2H2O (1) and CuL(ClO4)·4H2O (2) {L was condensed from equation molar salicylaldehyde and diethylenetriamine} have been synthesized and characterized. Further, two new bimetallic coordination polymers, {[ML][FeIIFeIII (ox)3] · 1.5H2O}∞ were synthesized and characterized, where ox2- = oxalate, M=Ni2+ (3) or Cu2+ (4). The tested results of elementary analysis of coordination polymers (3) and (4) were according with the theoretical value, and the results of the IR indicated that the coordination of oxalate were bridgetype in compound (3) and (4). 2-D layer coordination polymers were synthesized by oxalate and Fe3+, Fe2+. The result of M{\"o}ssbauer spectra of (3) and (4) in room temperature revealed that two different postural ferric ions were found in coordination polymer (3) and (4) ,and anions layer was formed by [FeII FeIII (ox)3]- unit. The compounds of (3) and (4) were bimetallic coordination polymers.",

keywords = "Bridging oxalate, Coordination polymer, Spectra characterization, Synthesis",

author = "Chen, {You Cun} and Liu, {Guang Xiang} and Hong Zhou and Ren, {Xiao Ming}",

year = "2002",

language = "英语",

volume = "22",

pages = "x16--812",

journal = "Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis",

issn = "1000-0593",

publisher = "Science China Press",

number = "5",

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TY - JOUR

T1 - Bimetallic Coordination Polymers {[ML] [FeII FeIII (ox)3] · 1.5H2O}infin with Layer Structure Syntheses, Spectra Characterization

AU - Chen, You Cun

AU - Liu, Guang Xiang

AU - Zhou, Hong

AU - Ren, Xiao Ming

PY - 2002

Y1 - 2002

N2 - Two new schiff base complexes, NiL(ClO4)·2H2O (1) and CuL(ClO4)·4H2O (2) {L was condensed from equation molar salicylaldehyde and diethylenetriamine} have been synthesized and characterized. Further, two new bimetallic coordination polymers, {[ML][FeIIFeIII (ox)3] · 1.5H2O}∞ were synthesized and characterized, where ox2- = oxalate, M=Ni2+ (3) or Cu2+ (4). The tested results of elementary analysis of coordination polymers (3) and (4) were according with the theoretical value, and the results of the IR indicated that the coordination of oxalate were bridgetype in compound (3) and (4). 2-D layer coordination polymers were synthesized by oxalate and Fe3+, Fe2+. The result of Mössbauer spectra of (3) and (4) in room temperature revealed that two different postural ferric ions were found in coordination polymer (3) and (4) ,and anions layer was formed by [FeII FeIII (ox)3]- unit. The compounds of (3) and (4) were bimetallic coordination polymers.

AB - Two new schiff base complexes, NiL(ClO4)·2H2O (1) and CuL(ClO4)·4H2O (2) {L was condensed from equation molar salicylaldehyde and diethylenetriamine} have been synthesized and characterized. Further, two new bimetallic coordination polymers, {[ML][FeIIFeIII (ox)3] · 1.5H2O}∞ were synthesized and characterized, where ox2- = oxalate, M=Ni2+ (3) or Cu2+ (4). The tested results of elementary analysis of coordination polymers (3) and (4) were according with the theoretical value, and the results of the IR indicated that the coordination of oxalate were bridgetype in compound (3) and (4). 2-D layer coordination polymers were synthesized by oxalate and Fe3+, Fe2+. The result of Mössbauer spectra of (3) and (4) in room temperature revealed that two different postural ferric ions were found in coordination polymer (3) and (4) ,and anions layer was formed by [FeII FeIII (ox)3]- unit. The compounds of (3) and (4) were bimetallic coordination polymers.

KW - Bridging oxalate

KW - Coordination polymer

KW - Spectra characterization

KW - Synthesis

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M3 - 文章

AN - SCOPUS:0347068994

SN - 1000-0593

VL - 22

SP - x16-812

JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

IS - 5

ER -

Bimetallic Coordination Polymers {[ML] [Fe^II Fe^III (ox)₃] · 1.5H₂O}_infin with Layer Structure Syntheses, Spectra Characterization

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