Bioinspired controlled synthesis of NiSe/Ni2P nanoparticles decorated 3D porous carbon for Li/Na ion batteries

Jun Yang; Nan Yang; Qian Xu; Low Sijia Pearlie; Yizhou Zhang; Ying Hong; Qian Wang; Wenjun Wang; Qingyu Yan; Xiaochen Dong

doi:10.1021/acssuschemeng.9b02478

Bioinspired controlled synthesis of NiSe/Ni₂P nanoparticles decorated 3D porous carbon for Li/Na ion batteries

Jun Yang, Nan Yang, Qian Xu, Low Sijia Pearlie, Yizhou Zhang, Ying Hong, Qian Wang, Wenjun Wang, Qingyu Yan, Xiaochen Dong

SCHOOL OF FLEXIBLE ELECTRONICS(FUTURE TECHNOLOGIES)|INSTITUTE OF ADVANCED MATERIALS(IAM)

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Three-dimensional (3D) porous carbon-encapsulated NiSe/Ni₂P nanoparticles (NiSe/Ni₂P/C) are synthesized via using the elastin-like polypeptides with hexahistidine tag (ELP16-His) followed by the selenization process and annealing treatment. The biochemistry-derived NiSe/Ni₂P nanoparticles (∼8 nm) have large specific surface area and are homogeneously dispersed in the 3D porous carbon matrix. It is found that the crystalline structure and morphologies of the product could be controlled with ELP16-His. As anodes in the application of lithium ion batteries (LIBs), the NiSe/Ni₂P/C presents high reversible capacities (911.3 mA h g^-1 at 100th cycle, 100 mA g^-1) and excellent rates behavior (220.7 mA h g^-1 at 10 A g^-1). In addition, high specific capacities of 353.6 mA h g^-1 (100th cycle, 100 mA g^-1) also can be achieved by NiSe/Ni₂P/C in sodium ion batteries (SIBs).

Original language	English
Pages (from-to)	13217-13225
Number of pages	9
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	15
DOIs	https://doi.org/10.1021/acssuschemeng.9b02478
State	Published - 5 Aug 2019

Keywords

3D porous carbon
Anode active materials
Batteries
Elastin-like polypeptides
NiSe/NiP nanoparticles

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This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/acssuschemeng.9b02478

Cite this

@article{c8fb2ac13f7341738c8d8b70ba9ca179,

title = "Bioinspired controlled synthesis of NiSe/Ni2P nanoparticles decorated 3D porous carbon for Li/Na ion batteries",

abstract = "Three-dimensional (3D) porous carbon-encapsulated NiSe/Ni2P nanoparticles (NiSe/Ni2P/C) are synthesized via using the elastin-like polypeptides with hexahistidine tag (ELP16-His) followed by the selenization process and annealing treatment. The biochemistry-derived NiSe/Ni2P nanoparticles (∼8 nm) have large specific surface area and are homogeneously dispersed in the 3D porous carbon matrix. It is found that the crystalline structure and morphologies of the product could be controlled with ELP16-His. As anodes in the application of lithium ion batteries (LIBs), the NiSe/Ni2P/C presents high reversible capacities (911.3 mA h g-1 at 100th cycle, 100 mA g-1) and excellent rates behavior (220.7 mA h g-1 at 10 A g-1). In addition, high specific capacities of 353.6 mA h g-1 (100th cycle, 100 mA g-1) also can be achieved by NiSe/Ni2P/C in sodium ion batteries (SIBs).",

keywords = "3D porous carbon, Anode active materials, Batteries, Elastin-like polypeptides, NiSe/NiP nanoparticles",

author = "Jun Yang and Nan Yang and Qian Xu and Pearlie, {Low Sijia} and Yizhou Zhang and Ying Hong and Qian Wang and Wenjun Wang and Qingyu Yan and Xiaochen Dong",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = aug,

day = "5",

doi = "10.1021/acssuschemeng.9b02478",

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T1 - Bioinspired controlled synthesis of NiSe/Ni2P nanoparticles decorated 3D porous carbon for Li/Na ion batteries

AU - Yang, Jun

AU - Yang, Nan

AU - Xu, Qian

AU - Pearlie, Low Sijia

AU - Zhang, Yizhou

AU - Hong, Ying

AU - Wang, Qian

AU - Wang, Wenjun

AU - Yan, Qingyu

AU - Dong, Xiaochen

PY - 2019/8/5

Y1 - 2019/8/5

N2 - Three-dimensional (3D) porous carbon-encapsulated NiSe/Ni2P nanoparticles (NiSe/Ni2P/C) are synthesized via using the elastin-like polypeptides with hexahistidine tag (ELP16-His) followed by the selenization process and annealing treatment. The biochemistry-derived NiSe/Ni2P nanoparticles (∼8 nm) have large specific surface area and are homogeneously dispersed in the 3D porous carbon matrix. It is found that the crystalline structure and morphologies of the product could be controlled with ELP16-His. As anodes in the application of lithium ion batteries (LIBs), the NiSe/Ni2P/C presents high reversible capacities (911.3 mA h g-1 at 100th cycle, 100 mA g-1) and excellent rates behavior (220.7 mA h g-1 at 10 A g-1). In addition, high specific capacities of 353.6 mA h g-1 (100th cycle, 100 mA g-1) also can be achieved by NiSe/Ni2P/C in sodium ion batteries (SIBs).

AB - Three-dimensional (3D) porous carbon-encapsulated NiSe/Ni2P nanoparticles (NiSe/Ni2P/C) are synthesized via using the elastin-like polypeptides with hexahistidine tag (ELP16-His) followed by the selenization process and annealing treatment. The biochemistry-derived NiSe/Ni2P nanoparticles (∼8 nm) have large specific surface area and are homogeneously dispersed in the 3D porous carbon matrix. It is found that the crystalline structure and morphologies of the product could be controlled with ELP16-His. As anodes in the application of lithium ion batteries (LIBs), the NiSe/Ni2P/C presents high reversible capacities (911.3 mA h g-1 at 100th cycle, 100 mA g-1) and excellent rates behavior (220.7 mA h g-1 at 10 A g-1). In addition, high specific capacities of 353.6 mA h g-1 (100th cycle, 100 mA g-1) also can be achieved by NiSe/Ni2P/C in sodium ion batteries (SIBs).

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KW - Anode active materials

KW - Batteries

KW - Elastin-like polypeptides

KW - NiSe/NiP nanoparticles

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