Bis(4-dimethylamino-1-ethylpyridinium) bis-(1,2-dicyanoethene-1,2- dithiolato-κ 2 S,S′)nickelate(II)

Shan Shan Yu; Hong Zhou; Xiao Ming Ren

doi:10.1107/S1600536812008161

Bis(4-dimethylamino-1-ethylpyridinium) bis-(1,2-dicyanoethene-1,2- dithiolato-κ ² S,S′)nickelate(II)

Shan Shan Yu, Hong Zhou, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The asymmetric unit of the title complex, (C ₉H ₁₅N ₂) ₂[Ni(C ₄N ₂S ₂) ₂], comprises one 4-dimethyl-amino-1-ethyl-pyri-din-ium cation and one half of a [Ni(mnt) ₂] ^2- (mnt ^2- = maleo-nitrile-dithiol-ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni ^II ion is coordinated by four S atoms of two mnt ^2- ligands and exhibits a square-planar coordination geometry.

Original language	English
Pages (from-to)	m395
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	4
DOIs	https://doi.org/10.1107/S1600536812008161
State	Published - Apr 2012

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title = "Bis(4-dimethylamino-1-ethylpyridinium) bis-(1,2-dicyanoethene-1,2- dithiolato-κ 2 S,S′)nickelate(II)",

abstract = "The asymmetric unit of the title complex, (C 9H 15N 2) 2[Ni(C 4N 2S 2) 2], comprises one 4-dimethyl-amino-1-ethyl-pyri-din-ium cation and one half of a [Ni(mnt) 2] 2- (mnt 2- = maleo-nitrile-dithiol-ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni II ion is coordinated by four S atoms of two mnt 2- ligands and exhibits a square-planar coordination geometry.",

author = "Yu, {Shan Shan} and Hong Zhou and Ren, {Xiao Ming}",

year = "2012",

month = apr,

doi = "10.1107/S1600536812008161",

language = "英语",

volume = "68",

pages = "m395",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Bis(4-dimethylamino-1-ethylpyridinium) bis-(1,2-dicyanoethene-1,2- dithiolato-κ 2 S,S′)nickelate(II)

AU - Yu, Shan Shan

AU - Zhou, Hong

AU - Ren, Xiao Ming

PY - 2012/4

Y1 - 2012/4

N2 - The asymmetric unit of the title complex, (C 9H 15N 2) 2[Ni(C 4N 2S 2) 2], comprises one 4-dimethyl-amino-1-ethyl-pyri-din-ium cation and one half of a [Ni(mnt) 2] 2- (mnt 2- = maleo-nitrile-dithiol-ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni II ion is coordinated by four S atoms of two mnt 2- ligands and exhibits a square-planar coordination geometry.

AB - The asymmetric unit of the title complex, (C 9H 15N 2) 2[Ni(C 4N 2S 2) 2], comprises one 4-dimethyl-amino-1-ethyl-pyri-din-ium cation and one half of a [Ni(mnt) 2] 2- (mnt 2- = maleo-nitrile-dithiol-ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni II ion is coordinated by four S atoms of two mnt 2- ligands and exhibits a square-planar coordination geometry.

UR - http://www.scopus.com/inward/record.url?scp=84860309562&partnerID=8YFLogxK

U2 - 10.1107/S1600536812008161

DO - 10.1107/S1600536812008161

M3 - 文章

AN - SCOPUS:84860309562

SN - 1600-5368

VL - 68

SP - m395

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Bis(4-dimethylamino-1-ethylpyridinium) bis-(1,2-dicyanoethene-1,2- dithiolato-κ ² S,S′)nickelate(II)

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