C- To N-Center Remote Heteroaryl Migration via Electrochemical Initiation of N Radical by Organic Catalyst

Chengkou Liu; Qiang Jiang; Yang Lin; Zheng Fang; Kai Guo

doi:10.1021/acs.orglett.9b04141

C- To N-Center Remote Heteroaryl Migration via Electrochemical Initiation of N Radical by Organic Catalyst

Chengkou Liu, Qiang Jiang, Yang Lin, Zheng Fang, Kai Guo

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Herein an exogenous oxidant- and metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.

Original language	English
Pages (from-to)	795-799
Number of pages	5
Journal	Organic Letters
Volume	22
Issue number	3
DOIs	https://doi.org/10.1021/acs.orglett.9b04141
State	Published - 7 Feb 2020

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abstract = "Herein an exogenous oxidant- and metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.",

author = "Chengkou Liu and Qiang Jiang and Yang Lin and Zheng Fang and Kai Guo",

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AU - Liu, Chengkou

AU - Jiang, Qiang

AU - Lin, Yang

AU - Fang, Zheng

AU - Guo, Kai

PY - 2020/2/7

Y1 - 2020/2/7

N2 - Herein an exogenous oxidant- and metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.

AB - Herein an exogenous oxidant- and metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.

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JO - Organic Letters

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C- To N-Center Remote Heteroaryl Migration via Electrochemical Initiation of N Radical by Organic Catalyst

Abstract

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