Carbodicarbenes-divalent carbon(0) compounds exhibiting carbon-carbon donor-acceptor bonds

Gernot Frenking; Ralf Tonner

doi:10.1002/wcms.53

Carbodicarbenes-divalent carbon(0) compounds exhibiting carbon-carbon donor-acceptor bonds

Gernot Frenking, Ralf Tonner

University of Marburg

Research output: Contribution to journal › Review article › peer-review

73 Scopus citations

Abstract

Theoretical and experimental studies of the recently introduced class of divalent carbon(0) compounds CL₂, wherein L is a carbene ligand, are described. Carbodicarbenes posses two donor-acceptor bonds between carbene ligands and a bare carbon atom that retains its four valence electrons as two lone pairs. Carbodicarbenes R₂C → C ← CR₂ are very strong Lewis bases. They are σ- and π-donors and thus may bind to two Lewis bases.

Original language	English
Pages (from-to)	869-878
Number of pages	10
Journal	Wiley Interdisciplinary Reviews: Computational Molecular Science
Volume	1
Issue number	6
DOIs	https://doi.org/10.1002/wcms.53
State	Published - Nov 2011
Externally published	Yes

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abstract = "Theoretical and experimental studies of the recently introduced class of divalent carbon(0) compounds CL2, wherein L is a carbene ligand, are described. Carbodicarbenes posses two donor-acceptor bonds between carbene ligands and a bare carbon atom that retains its four valence electrons as two lone pairs. Carbodicarbenes R2C → C ← CR2 are very strong Lewis bases. They are σ- and π-donors and thus may bind to two Lewis bases.",

author = "Gernot Frenking and Ralf Tonner",

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AB - Theoretical and experimental studies of the recently introduced class of divalent carbon(0) compounds CL2, wherein L is a carbene ligand, are described. Carbodicarbenes posses two donor-acceptor bonds between carbene ligands and a bare carbon atom that retains its four valence electrons as two lone pairs. Carbodicarbenes R2C → C ← CR2 are very strong Lewis bases. They are σ- and π-donors and thus may bind to two Lewis bases.

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Carbodicarbenes-divalent carbon(0) compounds exhibiting carbon-carbon donor-acceptor bonds

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