Carbodiphosphoranes: The chemistry of divalent carbon(0)

Ralf Tonner; Florian Öxler; Bernhard Neumüller; Wolfgang Petz; Gernot Frenking

doi:10.1002/anie.200602552

Carbodiphosphoranes: The chemistry of divalent carbon(0)

Ralf Tonner, Florian Öxler, Bernhard Neumüller, Wolfgang Petz, Gernot Frenking

University of Marburg

Research output: Contribution to journal › Article › peer-review

369 Scopus citations

Abstract

(Figure Presented) A combined experimental/theoretical study gives strong evidence that carbodiphosphoranes are divalent carbon(0) compounds. The calculations show that carbodiphosphoranes have two lone pairs of electrons (see picture), which give rise to unusual properties as confirmed by experiment. The synthesis of a triply charged molecules in which two protonated carbodiphosphoranes serve as donor ligands to an Ag⁺ center supports the bonding model.

Original language	English
Pages (from-to)	8038-8042
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	47
DOIs	https://doi.org/10.1002/anie.200602552
State	Published - 4 Dec 2006
Externally published	Yes

Keywords

Bonding analysis
Carbodiphosphoranes
Carbon
Cations
Donor-acceptor systems

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10.1002/anie.200602552

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AU - Öxler, Florian

AU - Neumüller, Bernhard

AU - Petz, Wolfgang

AU - Frenking, Gernot

PY - 2006/12/4

Y1 - 2006/12/4

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AB - (Figure Presented) A combined experimental/theoretical study gives strong evidence that carbodiphosphoranes are divalent carbon(0) compounds. The calculations show that carbodiphosphoranes have two lone pairs of electrons (see picture), which give rise to unusual properties as confirmed by experiment. The synthesis of a triply charged molecules in which two protonated carbodiphosphoranes serve as donor ligands to an Ag+ center supports the bonding model.

KW - Bonding analysis

KW - Carbodiphosphoranes

KW - Carbon

KW - Cations

KW - Donor-acceptor systems

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Carbodiphosphoranes: The chemistry of divalent carbon(0)

Abstract

Keywords

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