Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong Chua Teo; Kui Thong Tan; Teck Peng Loh

doi:10.1039/b412736f

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong Chua Teo, Kui Thong Tan, Teck Peng Loh

National University of Singapore

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

Original language	English
Pages (from-to)	1318-1320
Number of pages	3
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b412736f
State	Published - 14 Mar 2005
Externally published	Yes

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title = "Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex",

abstract = "A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).",

author = "Teo, {Yong Chua} and Tan, {Kui Thong} and Loh, {Teck Peng}",

year = "2005",

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doi = "10.1039/b412736f",

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journal = "Chemical Communications",

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AU - Teo, Yong Chua

AU - Tan, Kui Thong

AU - Loh, Teck Peng

PY - 2005/3/14

Y1 - 2005/3/14

N2 - A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

AB - A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

UR - http://www.scopus.com/inward/record.url?scp=16244388294&partnerID=8YFLogxK

U2 - 10.1039/b412736f

DO - 10.1039/b412736f

M3 - 文章

AN - SCOPUS:16244388294

SN - 1359-7345

SP - 1318

EP - 1320

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Abstract

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