Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

Yong Chua Teo; Ee Ling Goh; Teck Peng Loh

doi:10.1016/j.tetlet.2005.05.014

Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

Yong Chua Teo, Ee Ling Goh, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The ionic liquid [hmim][PF₆] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).

Original language	English
Pages (from-to)	4573-4575
Number of pages	3
Journal	Tetrahedron Letters
Volume	46
Issue number	27
DOIs	https://doi.org/10.1016/j.tetlet.2005.05.014
State	Published - 4 Jul 2005
Externally published	Yes

Keywords

Chiral indium complex
Enantioselective allylation
Ionic liquid
[hmim][PF]

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10.1016/j.tetlet.2005.05.014

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title = "Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids",

abstract = "The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).",

keywords = "Chiral indium complex, Enantioselective allylation, Ionic liquid, [hmim][PF]",

author = "Teo, {Yong Chua} and Goh, {Ee Ling} and Loh, {Teck Peng}",

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journal = "Tetrahedron Letters",

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AU - Teo, Yong Chua

AU - Goh, Ee Ling

AU - Loh, Teck Peng

PY - 2005/7/4

Y1 - 2005/7/4

N2 - The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).

AB - The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).

KW - Chiral indium complex

KW - Enantioselective allylation

KW - Ionic liquid

KW - [hmim][PF]

UR - http://www.scopus.com/inward/record.url?scp=20344379662&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2005.05.014

DO - 10.1016/j.tetlet.2005.05.014

M3 - 文章

AN - SCOPUS:20344379662

SN - 0040-4039

VL - 46

SP - 4573

EP - 4575

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 27

ER -

Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

Abstract

Keywords

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