Catalytic enantioselective allylation of ketones via a chiral indium(III) complex

Yong Chua Teo; Joshua Daniel Goh; Teck Peng Loh

doi:10.1021/ol051018n

Catalytic enantioselective allylation of ketones via a chiral indium(III) complex

Yong Chua Teo, Joshua Daniel Goh, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

(Chemical Equation Presented) A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).

Original language	English
Pages (from-to)	2743-2745
Number of pages	3
Journal	Organic Letters
Volume	7
Issue number	13
DOIs	https://doi.org/10.1021/ol051018n
State	Published - 2005
Externally published	Yes

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title = "Catalytic enantioselective allylation of ketones via a chiral indium(III) complex",

abstract = "(Chemical Equation Presented) A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).",

author = "Teo, {Yong Chua} and Goh, {Joshua Daniel} and Loh, {Teck Peng}",

year = "2005",

doi = "10.1021/ol051018n",

language = "英语",

volume = "7",

pages = "2743--2745",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "13",

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TY - JOUR

T1 - Catalytic enantioselective allylation of ketones via a chiral indium(III) complex

AU - Teo, Yong Chua

AU - Goh, Joshua Daniel

AU - Loh, Teck Peng

PY - 2005

Y1 - 2005

N2 - (Chemical Equation Presented) A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).

AB - (Chemical Equation Presented) A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).

UR - http://www.scopus.com/inward/record.url?scp=23744446171&partnerID=8YFLogxK

U2 - 10.1021/ol051018n

DO - 10.1021/ol051018n

M3 - 文章

AN - SCOPUS:23744446171

SN - 1523-7060

VL - 7

SP - 2743

EP - 2745

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Catalytic enantioselective allylation of ketones via a chiral indium(III) complex

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