TY - JOUR
T1 - Catalytic production of liquid hydrocarbon fuels and fuel additives from lignocellulosic platform molecules
AU - Zhu, Chenjie
AU - Du, Fengguang
AU - Ying, Hanjie
AU - Ouyang, Pingkai
N1 - Publisher Copyright:
©, 2015, Chemical Industry Press. All right reserved.
PY - 2015/8/1
Y1 - 2015/8/1
N2 - Development and utilization of renewable biomass resources has great significance in easing the energy crisis and reducing environmental pollution. Lignocellulosic biomass is much more concerned due to its abundant reserves, lower cost and fast-growing. In this work some relevant processes for the preparation of liquid hydrocarbon fuels and fuel additives from lignocellulosic platform molecules are discussed and summarized. Catalytic transformation of these platform molecules for the production of liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation) with the increase of molecular weight via C-C coupling reactions (e.g. aldol condensation, hydroxyalkylation, ketonization, oligomerization). Moreover, it is shown that these platform molecules can also be converted into a variety of fuel additives through catalytic transformations that include reduction, esterification, etherification, and acetalization reactions. The catalysts and processes involved in these catalytic routes are intensively discussed, and their existing problems as well as possible solutions are addressed, which may provide insights helpful for further studies on the valorization of lignocellulose for energy.
AB - Development and utilization of renewable biomass resources has great significance in easing the energy crisis and reducing environmental pollution. Lignocellulosic biomass is much more concerned due to its abundant reserves, lower cost and fast-growing. In this work some relevant processes for the preparation of liquid hydrocarbon fuels and fuel additives from lignocellulosic platform molecules are discussed and summarized. Catalytic transformation of these platform molecules for the production of liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation) with the increase of molecular weight via C-C coupling reactions (e.g. aldol condensation, hydroxyalkylation, ketonization, oligomerization). Moreover, it is shown that these platform molecules can also be converted into a variety of fuel additives through catalytic transformations that include reduction, esterification, etherification, and acetalization reactions. The catalysts and processes involved in these catalytic routes are intensively discussed, and their existing problems as well as possible solutions are addressed, which may provide insights helpful for further studies on the valorization of lignocellulose for energy.
KW - Bioenergy
KW - Biofuel
KW - Biomass
KW - Lignocellulose
KW - Platform molecules
UR - http://www.scopus.com/inward/record.url?scp=85050578109&partnerID=8YFLogxK
U2 - 10.11949/j.issn.0438-1157.20150635
DO - 10.11949/j.issn.0438-1157.20150635
M3 - 文献综述
AN - SCOPUS:85050578109
SN - 0438-1157
VL - 66
SP - 2784
EP - 2794
JO - Huagong Xuebao/CIESC Journal
JF - Huagong Xuebao/CIESC Journal
IS - 8
ER -