Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

Yan Xu; Dun Ru Zhu; Zi Jian Guo; Yu Jun Shi; Kou Lin Zhang; Xiao Zeng You

doi:10.1039/b010227j

Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

Yan Xu, Dun Ru Zhu, Zi Jian Guo, Yu Jun Shi, Kou Lin Zhang, Xiao Zeng You

Nanjing University

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Two novel hexadecametal-oxygen cluster compounds, {Ni[(NH₂) ₂(C₂H₄)₂NH]₂} ₃[PMo^VI₅Mo^V₃V ^IV₈O₄₄]·[(NH₂) ₂-(C₂H₄)₂NH]·H₂O 1 and {Co[(NH₂)₂(C₂H₄) ₂NH]₂}₂Na-[PMo^VI₆Mo ^V₂V^IV₈O₄₄]·8H ₂O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal-oxygen host shell is observed in 2.

Original language	English
Pages (from-to)	772-773
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	6
DOIs	https://doi.org/10.1039/b010227j
State	Published - 2001
Externally published	Yes

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title = "Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions",

abstract = "Two novel hexadecametal-oxygen cluster compounds, {Ni[(NH2) 2(C2H4)2NH]2} 3[PMoVI5MoV3V IV8O44]·[(NH2) 2-(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4) 2NH]2}2Na-[PMoVI6Mo V2VIV8O44]·8H 2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal-oxygen host shell is observed in 2.",

author = "Yan Xu and Zhu, {Dun Ru} and Guo, {Zi Jian} and Shi, {Yu Jun} and Zhang, {Kou Lin} and You, {Xiao Zeng}",

year = "2001",

doi = "10.1039/b010227j",

language = "英语",

pages = "772--773",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "6",

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T1 - Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

AU - Xu, Yan

AU - Zhu, Dun Ru

AU - Guo, Zi Jian

AU - Shi, Yu Jun

AU - Zhang, Kou Lin

AU - You, Xiao Zeng

PY - 2001

Y1 - 2001

N2 - Two novel hexadecametal-oxygen cluster compounds, {Ni[(NH2) 2(C2H4)2NH]2} 3[PMoVI5MoV3V IV8O44]·[(NH2) 2-(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4) 2NH]2}2Na-[PMoVI6Mo V2VIV8O44]·8H 2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal-oxygen host shell is observed in 2.

AB - Two novel hexadecametal-oxygen cluster compounds, {Ni[(NH2) 2(C2H4)2NH]2} 3[PMoVI5MoV3V IV8O44]·[(NH2) 2-(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4) 2NH]2}2Na-[PMoVI6Mo V2VIV8O44]·8H 2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal-oxygen host shell is observed in 2.

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DO - 10.1039/b010227j

M3 - 文章

AN - SCOPUS:0035925862

SN - 1470-479X

SP - 772

EP - 773

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 6

ER -

Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

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