Cesium carbonate-catalyzed indium insertion into alkyl iodides and their synthetic utilities in cross-coupling reactions

Xue Xin Feng; Zhen Wu; Qing Dong Wang; Bing Zhi Chen; Weidong Rao; Jin Ming Yang; Zhi Liang Shen

doi:10.1002/aoc.5110

Cesium carbonate-catalyzed indium insertion into alkyl iodides and their synthetic utilities in cross-coupling reactions

Xue Xin Feng, Zhen Wu, Qing Dong Wang, Bing Zhi Chen, Weidong Rao, Jin Ming Yang, Zhi Liang Shen

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A catalytic amount of cesium carbonate (10 mol%) was found to be capable of effectively catalyzing the insertion of indium powder into alkyl iodides. The thus-generated alkyl indium reagents could readily undergo palladium-catalyzed cross-coupling reactions with a wide variety of aryl halides, showing compatibility to a range of important functional groups.

Original language	English
Article number	e5110
Journal	Applied Organometallic Chemistry
Volume	33
Issue number	9
DOIs	https://doi.org/10.1002/aoc.5110
State	Published - 2019

Keywords

alkyl indium reagent
cesium carbonate
cross-coupling reaction
indium
palladium

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title = "Cesium carbonate-catalyzed indium insertion into alkyl iodides and their synthetic utilities in cross-coupling reactions",

abstract = "A catalytic amount of cesium carbonate (10 mol%) was found to be capable of effectively catalyzing the insertion of indium powder into alkyl iodides. The thus-generated alkyl indium reagents could readily undergo palladium-catalyzed cross-coupling reactions with a wide variety of aryl halides, showing compatibility to a range of important functional groups.",

keywords = "alkyl indium reagent, cesium carbonate, cross-coupling reaction, indium, palladium",

author = "Feng, {Xue Xin} and Zhen Wu and Wang, {Qing Dong} and Chen, {Bing Zhi} and Weidong Rao and Yang, {Jin Ming} and Shen, {Zhi Liang}",

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AU - Feng, Xue Xin

AU - Wu, Zhen

AU - Wang, Qing Dong

AU - Chen, Bing Zhi

AU - Rao, Weidong

AU - Yang, Jin Ming

AU - Shen, Zhi Liang

PY - 2019

Y1 - 2019

N2 - A catalytic amount of cesium carbonate (10 mol%) was found to be capable of effectively catalyzing the insertion of indium powder into alkyl iodides. The thus-generated alkyl indium reagents could readily undergo palladium-catalyzed cross-coupling reactions with a wide variety of aryl halides, showing compatibility to a range of important functional groups.

AB - A catalytic amount of cesium carbonate (10 mol%) was found to be capable of effectively catalyzing the insertion of indium powder into alkyl iodides. The thus-generated alkyl indium reagents could readily undergo palladium-catalyzed cross-coupling reactions with a wide variety of aryl halides, showing compatibility to a range of important functional groups.

KW - alkyl indium reagent

KW - cesium carbonate

KW - cross-coupling reaction

KW - indium

KW - palladium

UR - http://www.scopus.com/inward/record.url?scp=85069668128&partnerID=8YFLogxK

U2 - 10.1002/aoc.5110

DO - 10.1002/aoc.5110

M3 - 文章

AN - SCOPUS:85069668128

SN - 0268-2605

VL - 33

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 9

M1 - e5110

ER -

Cesium carbonate-catalyzed indium insertion into alkyl iodides and their synthetic utilities in cross-coupling reactions

Abstract

Keywords

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