CF22+ and CF2+, two unusually stable dications with carbon-fluorine double bonding

Wolfram Koch; Gernot Frenking

doi:10.1016/0009-2614(85)85082-X

CF₂²⁺ and CF²⁺, two unusually stable dications with carbon-fluorine double bonding

Wolfram Koch, Gernot Frenking

Technical University of Berlin

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Ab initio calculations at MP2/6·31G^*//MP2/6·31G^* level of theory predict that CF₂²⁺ and CF²⁺ are very stable dications which in spite of strong Coulomb repulsion contain carbon-fluorine double bonding.

Original language	English
Pages (from-to)	178-181
Number of pages	4
Journal	Chemical Physics Letters
Volume	114
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(85)85082-X
State	Published - 22 Feb 1985
Externally published	Yes

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title = "CF22+ and CF2+, two unusually stable dications with carbon-fluorine double bonding",

abstract = "Ab initio calculations at MP2/6·31G*//MP2/6·31G* level of theory predict that CF22+ and CF2+ are very stable dications which in spite of strong Coulomb repulsion contain carbon-fluorine double bonding.",

author = "Wolfram Koch and Gernot Frenking",

year = "1985",

month = feb,

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doi = "10.1016/0009-2614(85)85082-X",

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T1 - CF22+ and CF2+, two unusually stable dications with carbon-fluorine double bonding

AU - Koch, Wolfram

AU - Frenking, Gernot

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Y1 - 1985/2/22

N2 - Ab initio calculations at MP2/6·31G*//MP2/6·31G* level of theory predict that CF22+ and CF2+ are very stable dications which in spite of strong Coulomb repulsion contain carbon-fluorine double bonding.

AB - Ab initio calculations at MP2/6·31G*//MP2/6·31G* level of theory predict that CF22+ and CF2+ are very stable dications which in spite of strong Coulomb repulsion contain carbon-fluorine double bonding.

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U2 - 10.1016/0009-2614(85)85082-X

DO - 10.1016/0009-2614(85)85082-X

M3 - 文章

AN - SCOPUS:0001392874

SN - 0009-2614

VL - 114

SP - 178

EP - 181

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

CF₂²⁺ and CF²⁺, two unusually stable dications with carbon-fluorine double bonding

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