Change of critical supersaturation ratio in CaCO3 scale formation

Xiaoshuang Yin; Wenzhong Yang; Yongming Tang; Ying Liu; Chen Thou

Change of critical supersaturation ratio in CaCO₃ scale formation

Xiaoshuang Yin, Wenzhong Yang, Yongming Tang, Ying Liu, Chen Thou

School of Chemistry and Moleculai Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The effects of solution temperature, contact time of fouling ions, type and concentration of scale inhibitors on critical supersaturation ratio (CSSR) of CaCO₃ solution were evaluated. The change of surface free energy during crystallizing of CaCO₃ in presence of scale inhibitors was studied according to the light of homogeneous nucleation theory. In the presence of aminotrimethylene phosphonic acid (ATMP), CSSR decreased more with the increase of temperature than that in the presence of 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) or polyacrylic acid (PAA). The effect of CaCO₃ nucleation with PBTCA and ATMP on surface free energy was more obvious than that with PAA. Crystalline form of CaCO₃ precipitate transformed from calcite in main into vaterite in main in the presence of scale inhibitors.

Original language	English
Pages (from-to)	467-471
Number of pages	5
Journal	Petrochemical Technology
Volume	36
Issue number	5
State	Published - 15 May 2007

Keywords

2 - Phosphonobutane - 1,2,4 - tricarboxylic acid
Aminotrimethylene phosphonic acid
Calcium carbonate
Critical supersaturation ratio
Poly (acrylic acid)
Scale - inhibitor

Cite this

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title = "Change of critical supersaturation ratio in CaCO3 scale formation",

abstract = "The effects of solution temperature, contact time of fouling ions, type and concentration of scale inhibitors on critical supersaturation ratio (CSSR) of CaCO3 solution were evaluated. The change of surface free energy during crystallizing of CaCO3 in presence of scale inhibitors was studied according to the light of homogeneous nucleation theory. In the presence of aminotrimethylene phosphonic acid (ATMP), CSSR decreased more with the increase of temperature than that in the presence of 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) or polyacrylic acid (PAA). The effect of CaCO3 nucleation with PBTCA and ATMP on surface free energy was more obvious than that with PAA. Crystalline form of CaCO3 precipitate transformed from calcite in main into vaterite in main in the presence of scale inhibitors.",

keywords = "2 - Phosphonobutane - 1,2,4 - tricarboxylic acid, Aminotrimethylene phosphonic acid, Calcium carbonate, Critical supersaturation ratio, Poly (acrylic acid), Scale - inhibitor",

author = "Xiaoshuang Yin and Wenzhong Yang and Yongming Tang and Ying Liu and Chen Thou",

year = "2007",

month = may,

day = "15",

language = "英语",

volume = "36",

pages = "467--471",

journal = "Petrochemical Technology",

issn = "1000-8144",

publisher = "Beijing Research Institute of Chemical Industry",

number = "5",

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TY - JOUR

T1 - Change of critical supersaturation ratio in CaCO3 scale formation

AU - Yin, Xiaoshuang

AU - Yang, Wenzhong

AU - Tang, Yongming

AU - Liu, Ying

AU - Thou, Chen

PY - 2007/5/15

Y1 - 2007/5/15

N2 - The effects of solution temperature, contact time of fouling ions, type and concentration of scale inhibitors on critical supersaturation ratio (CSSR) of CaCO3 solution were evaluated. The change of surface free energy during crystallizing of CaCO3 in presence of scale inhibitors was studied according to the light of homogeneous nucleation theory. In the presence of aminotrimethylene phosphonic acid (ATMP), CSSR decreased more with the increase of temperature than that in the presence of 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) or polyacrylic acid (PAA). The effect of CaCO3 nucleation with PBTCA and ATMP on surface free energy was more obvious than that with PAA. Crystalline form of CaCO3 precipitate transformed from calcite in main into vaterite in main in the presence of scale inhibitors.

AB - The effects of solution temperature, contact time of fouling ions, type and concentration of scale inhibitors on critical supersaturation ratio (CSSR) of CaCO3 solution were evaluated. The change of surface free energy during crystallizing of CaCO3 in presence of scale inhibitors was studied according to the light of homogeneous nucleation theory. In the presence of aminotrimethylene phosphonic acid (ATMP), CSSR decreased more with the increase of temperature than that in the presence of 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) or polyacrylic acid (PAA). The effect of CaCO3 nucleation with PBTCA and ATMP on surface free energy was more obvious than that with PAA. Crystalline form of CaCO3 precipitate transformed from calcite in main into vaterite in main in the presence of scale inhibitors.

KW - 2 - Phosphonobutane - 1,2,4 - tricarboxylic acid

KW - Aminotrimethylene phosphonic acid

KW - Calcium carbonate

KW - Critical supersaturation ratio

KW - Poly (acrylic acid)

KW - Scale - inhibitor

UR - http://www.scopus.com/inward/record.url?scp=34250312841&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:34250312841

SN - 1000-8144

VL - 36

SP - 467

EP - 471

JO - Petrochemical Technology

JF - Petrochemical Technology

IS - 5

ER -

Change of critical supersaturation ratio in CaCO₃ scale formation

Abstract

Keywords

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